A series of [Formula: see text] crystals with various [Li]/[Nb] ratios (0.946, 1.05, 1.20 and 1.38) were grown by the Czochralski method. They were analyzed by inductively coupled plasma atomic emission spectroscopy (ICP-AES). As the [Li]/[Nb] ratio increases in the melt, the segregation coefficients of [Formula: see text] and [Formula: see text] ions increase, while the segregation coefficient of [Formula: see text] ions decrease. The [Li]/[Nb] ratio in the crystal of sample [Formula: see text] is 0.996, which is near stoichiometric. The dopant occupancy with different [Li]/[Nb] ratios was analyzed by IR transmission spectrum and UV-VIS-NIR spectrum. When the [Li]/[Nb] ratio reaches 1.20, the absorption peak at [Formula: see text] indicates that the threshold concentration of [Formula: see text] is 1 mol.% in the sample [Formula: see text].