Free Radical-initiated Reaction of Ethylene with Carbon Tetrachloride

Joyce, Robert M.; Hanford, W. E.; Harmon, John B.

doi:10.1021/ja01187a067

Cited by 84 publications

(14 citation statements)

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“…With water it forms a hydratelike addition compound which decomposes at þ 1. 45 C. The telomerization of ethylene and vinyl derivatives with tetrachloromethane under pressure and in the presence of peroxides has acquired a certain preparative significance [22][23][24]:…”

Section: Chemical Propertiesmentioning

confidence: 99%

Chloromethanes

Rossberg¹,

Lendle²,

Pfleiderer³

et al. 2011

Ullmann's Encyclopedia of Industrial Chemistry

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Section: Chemical Propertiesmentioning

confidence: 99%

Chloromethanes

Rossberg¹,

Lendle²,

Pfleiderer³

et al. 2011

Ullmann's Encyclopedia of Industrial Chemistry

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“…A telomerization reaction differs from a polymerization reaction by the presence in the reaction medium of a chain transfer agent (telogen) whose role is to limit the length of the macromolecular chain and to permit to obtain polymers with low degrees of polymerization (DP n ). These oligomers are called telomers. , …”

Section: Introductionmentioning

confidence: 99%

Polyanion Inhibitors of Human Immunodeficiency Virus and Other Viruses. 5. Telomerized Anionic Surfactants Derived from Amino Acids

et al. 1997

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omega-Acryloyl anionic surfactants, whose polar heads are derived from amino acids, have been telomerized to prepare polyanions of a predetermined molecular weight. The main goal of this study was to verify whether the antiviral activity is influenced by the degree of polymerization of the polyanions. The oligomeric polyanions were evaluated for their activity against human immunodeficiency virus (HIV-1 or HIV-2) and various other RNA and DNA viruses. With regard to their anti-HIV activity, a minimum number of anionic groups was necessary to achieve an inhibitory effect. Moreover, to be active the overall conformation of the polyanion must be such that the anionic groups are located on the external site of the molecule. With some of the polyanions, a 50% inhibition concentration (IC50) as low as 1 microgram/ mL, or even 0.1 microgram/mL, was noted against HIV-1 in CEM-4 and MT-4 cells, respectively. The most potent polyanions also proved active against human cytomegalovirus and herpex simplex virus at concentrations of 5-10 and 20-40 micrograms/mL, respectively. No activity was observed against any of the other viruses tested (i.e., vesicular stomatitis, Sindbis, Semliki forest, parainfluenza, Junin, Tacaribe, Coxsackie, polio, reo, and vaccinia). No toxicity for the host cells was observed at concentrations up to 200 micrograms/mL.

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“…Soon after the discovery of the Kharasch addition, it was found that small olefins may form telomers [56] (Fig. 36):…”

Section: Telomerization Of Small Olefins As a Way To Long-chain Pcamentioning

confidence: 99%

“…36) [56] A stainless steel-lined tubular pressure reactor having an internal volume of about 350 mL and equipped with a thermocouple well and gas inlet was charged with 210 g. (1.36 moles) of freshly distilled carbon tetrachloride, 35 g. of water, and 0.47 g. (0.00194 mole) of benzoyl peroxide ("Lucidol"). The reactor was evacuated, pressured to 500 lb./sq.…”

Section: 1-dichlorononanementioning

confidence: 99%

Synthesis of Polychloroalkanes

Nikiforov

2010

The Handbook of Environmental Chemistry

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This chapter describes the preparation of polychloroalkanes (chlorinated paraffines, PCA) as analytical standards. A list of commercially available PCA standards is given. General methods for the synthesis of PCAs are reviewed. Possibilities of the synthesis of other PCA congeners as standards are discussed. References to the original syntheses are tabulated. A selection of synthetic procedures is collected in the Appendix.

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Free Radical-initiated Reaction of Ethylene with Carbon Tetrachloride

Cited by 84 publications

References 0 publications

Chloromethanes

Chloromethanes

Polyanion Inhibitors of Human Immunodeficiency Virus and Other Viruses. 5. Telomerized Anionic Surfactants Derived from Amino Acids

Synthesis of Polychloroalkanes

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