A large number of joint friction pairs work during the work of scroll compressors, resulting in high energy consumption and short service life of scroll compressors. To improve the tribological performance of friction pairs of the scroll compressors, the C-MoS2-PTFE (Polytetrafluoroethylene) lubrication coating is prepared through spraying technology on the surface of 4032 aluminum alloy, a common material for scroll compressors. The microstructure of the C-MoS2-PTFE coating was analyzed by X-ray diffractometer (XRD) and scanning electron microscope (SEM), and the wear behavior of the coating under different loads was studied by reciprocating friction and wear testing machine and three-dimensional profiler. The surface of the grinding marks was analyzed by SEM and energy density spectrum (EDS). The performance was compared with the anodized film of 4032 aluminum alloy and the Ni-coated coating of 4032 aluminum alloy. The experimental results show that the C-MoS2-PTFE coating has a dense structure, and the hardness is 35 HV0.1. Under dry friction conditions, the C-MoS2-PTFE coating has excellent wear reduction and wear resistance, and the coefficient of friction and wears rate under different loads are less than those of the anodized film of 4032 aluminum alloy and the Ni-plated coating. The wear mechanisms of C-MoS2-PTFE coating are fatigue wear, adhesive wear, abrasive wear, and oxidation wear under different loads.