2015
DOI: 10.1016/j.tsf.2015.01.044
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Friction behaviour of TiAlN films around cubic/hexagonal transition: A 2D grazing incidence X-ray diffraction and electron energy loss spectroscopy study

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Cited by 9 publications
(4 citation statements)
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“…For an easy comparison of our ELNES spectra with those XANES experiments, we used the same labels as in [55]: H for the first bump of Ti-rich films and I, J, and K for the three-peaked structure observed in Al-rich films. It has been well reproduced by DFT calculations [56] and is obviously related to the contribution of N sites surrounded by four metal atoms in wurtzite arrangements [18]. The presence of a shoulder at the energy of the H structure in the Ti0.14Al0.86N spectrum, which is missing in w-AlN, has been assigned to the presence of sixfold-coordinated nitrogen out of the hcp columns of Al-rich nitrides [15].…”
Section: Friction Testsmentioning
confidence: 88%
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“…For an easy comparison of our ELNES spectra with those XANES experiments, we used the same labels as in [55]: H for the first bump of Ti-rich films and I, J, and K for the three-peaked structure observed in Al-rich films. It has been well reproduced by DFT calculations [56] and is obviously related to the contribution of N sites surrounded by four metal atoms in wurtzite arrangements [18]. The presence of a shoulder at the energy of the H structure in the Ti0.14Al0.86N spectrum, which is missing in w-AlN, has been assigned to the presence of sixfold-coordinated nitrogen out of the hcp columns of Al-rich nitrides [15].…”
Section: Friction Testsmentioning
confidence: 88%
“…So, it is worth looking closely at the nitrogen bonding within the two components of the multilayer. ELNES spectra of standard Ti1-xAlxN films prepared in roughly the same deposition conditions as the multilayer, Ti0.54Al0.46N, TiN and Al-rich Ti0.14Al0.86N [18], are presented together with the spectra recorded at the centre of each of the metallic and nitride layers of the multilayer in Figs. 10a and 10b respectively.…”
Section: Friction Testsmentioning
confidence: 99%
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“…Thin metallic Ti 1-x Al x interlayers of thickness 45 nm have been deposited before the Ti 1-x Al x N coatings for enhancing adhesion. More details of the elaboration process and targets used are described in earlier work (Pinot et al, 2015).…”
Section: Sample Elaborationmentioning
confidence: 99%