Flexible bioelectric dry electrodes are an important
part of long-term
medical healthcare monitoring systems. In this study, a new method
is proposed for the preparation of dry electrodes with micronanopillar
arrays structured by designing dimensionally tunable anodized aluminum
oxide (AAO) templates, by which polyaniline/thermoplastic polyurethane
single-layer micronanopillar array structured dry electrodes (PANI/TPU-SE)
and polyaniline/thermoplastic polyurethane double-layer micronanopillar
array structured dry electrodes (PANI/TPU-DE) are prepared. Compared
with the planar structure, the micronanopillar array structure can
reduce the contact gap between the electrode and skin and increase
the contact area, thus exhibiting lower contact impedance and higher
signal quality. At 0.1 Hz, the impedances of the wet electrode, PANI/TPU-DE300,
PANI/TPU-SE10, and planar structure electrodes are 269.5 kΩ,
375.5 kΩ, 398.1 kΩ, and 2.257 MΩ, respectively,
and the impedance value for PANI/TPU-DE300 is smaller than that for
PANI/TPU-SE10 and closer to that for the wet electrode. In addition,
because the surface of the micronanostructure can conform to the human
skin, about 210.7% increase in the peel strength of double-layer structure
electrodes compared to flat structure electrodes, it shows a low baseline
drift in the dynamic ECG measurement, and the signal-to-noise ratio
in the walking state can reach 21.33 ± 5.4775 dB. Therefore,
the prepared bioelectric dry electrode has a wide application prospect
in the fields of wearable medical monitoring.