FT-IR and Raman spectroscopic and quantum chemical studies of zinc halide complexes with 2,2′-biquinoline

Özel, Ayşen E.; Kecel, Serda; Akyüz, Sevim

doi:10.1016/j.vibspec.2008.01.010

Cited by 5 publications

(1 citation statement)

References 19 publications

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“…Assignment of the bands at this region is rather difficult and speculative as the bands of biq can overlap the bands of ccnm. The most characteristic bands of complex (I) exhibit no significant differences from those in similar complexes (Vitushkina et al, 2017;Ozel et al, 2008).…”

Section: Ir Spectroscopymentioning

confidence: 79%

A Cu^II complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

et al. 2018

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The complex (2,2'-biquinoline-κN,N')(carbamoylcyanonitrosomethanide-κN,O)chloridocopper(II) acetonitrile monosolvate, [Cu(CHNO)Cl(CHN)]·CHCN or [Cu(ccnm)Cl(biq)]·acn (acn is acetonitrile, biq is 2,2'-biquinoline and ccnm is carbamoylcyanonitrosomethanide), (I), was prepared as a result of nucleophilic addition of water to the dicyanonitrosomethanide ion in the presence of Cu and biq. IR spectroscopy confirmed the presence of ccnm, biq and acn in (I). The solid-state structure consists of the neutral complex containing ccnm and biq ligands, coordinated to the Cu atom in a bidendate chelating manner, and a chloride ligand, resulting in a distorted tetragonal pyramidal coordination of Cu. The asymmetric unit is supplemented by one molecule of solvated acn which, along with the nitrile group of ccnm, serves as an acceptor in intermolecular hydrogen bonding, creating infinite chains along the b axis. Magnetic measurements revealed a paramagnetic behaviour with a very small Weiss temperature Θ = -0.32 K and high anisotropy of the g tensor (g = 2.036, g = 2.120 and g = 2.205).

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Section: Ir Spectroscopymentioning

confidence: 79%

A Cu^II complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

et al. 2018

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Structural study, intermolecular interactions in view of X-ray and Hirshfeld surface analysis, DSC characterization, and electrical properties of bis-(4-benzylpyridinium) tetrabromozincate

Chihaoui

Hamdi

Zouari

2016

Ionics

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Three new Ag(I) thiosaccharinate complexes: Synthesis, structural studies, spectral characterization and theoretical analysis

Burrow

Belmonte

Dennehy

2016

Inorganica Chimica Acta

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FT-IR and Raman spectroscopic and quantum chemical studies of zinc halide complexes with 2,2′-biquinoline

Cited by 5 publications

References 19 publications

A Cu^II complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

A Cu^II complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

Structural study, intermolecular interactions in view of X-ray and Hirshfeld surface analysis, DSC characterization, and electrical properties of bis-(4-benzylpyridinium) tetrabromozincate

Three new Ag(I) thiosaccharinate complexes: Synthesis, structural studies, spectral characterization and theoretical analysis

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FT-IR and Raman spectroscopic and quantum chemical studies of zinc halide complexes with 2,2′-biquinoline

Cited by 5 publications

References 19 publications

A CuII complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

A CuII complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

Structural study, intermolecular interactions in view of X-ray and Hirshfeld surface analysis, DSC characterization, and electrical properties of bis-(4-benzylpyridinium) tetrabromozincate

Three new Ag(I) thiosaccharinate complexes: Synthesis, structural studies, spectral characterization and theoretical analysis

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A Cu^II complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties

A Cu^II complex with an carbamoylcyanonitrosomethanide ligand formed in situ by the nucleophilic addition of water to dicyanonitrosomethanide: structure, spectral and magnetic properties