Functional multilayer coatings of tetravinylsilane

Structure of Plasma‐Deposited Poly(acrylic acid) Films

“…In literature, the characterization of the physicochemical properties of thin organic plasma polymerized layers concentrates on films used as scratch protection finishing or on polymers which can replace brittle metallic or ceramic components in electronic circuits 3, 4. For instance Cech et al5, 6 measured the mechanical (elastic modulus and hardness) and optical properties of plasma polymerized silane layers (tetravinylsilane and vinyltriethoxysilane) in dependence on the effective power of the plasma. Besides the mechanical properties of the plasma polymerized films, their electrical and dielectric properties are of great importance.…”

Ionic Chemistry of Tetravinylsilane Cation (TVS+) Formed by Electron Impact: Theory and Experiment

“…Finally, the ionization energy of TVS was deduced from the earlier photoelectron spectrum of Schweig et al In contrast, nothing is available in the literature concerning the TVS + ion despite its importance, at least on plasma physics. Indeed, TVS + is suspected to be present and involved during the formation of TVS polymer films. − These experimental works suggest also the occurrence of isomerization processes under these conditions, resulting in functional multilayer organosilicon surfaces with new physicochemical properties and therefore important industrial applications.…”

“…Indeed, TVS + is suspected to be present and involved during the formation of TVS polymer films. [15][16][17] These experimental works suggest also the occurrence of isomerization processes under these conditions, resulting in functional multilayer organosilicon surfaces with new physicochemical properties and therefore important industrial applications.…”