Amphiphilic polymer water-dispersed polyester (WPET)
has an important
application value in the textile field. However, due to the potential
interactions among water-dispersed polyester (WPET) molecules, the
stability of their solution is susceptible to external factors. This
paper focused on the self-assembly properties and aggregation behavior
of amphiphilic water-dispersed polyester with different contents of
sulfonate groups. In addition, the effects of WPET concentration,
temperature, and Na+, Mg2+, or Ca2+ on WPET aggregation behavior were systematically investigated. The
results show that compared with the low sulfonate group content of
WPET, the high sulfonate group content of the WPET dispersion has
higher stability with or without a high electrolyte concentration.
In contrast, dispersions with low sulfonate group content are very
sensitive to electrolytes and aggregate immediately at low ionic strength.
WPET concentration, temperature, and electrolyte play important and
complex roles in controlling the self-assembly properties and aggregation
behavior of the WPET. The increase in WPET concentration can promote
the self-assembly of WPET molecules. With the increase in temperature,
the self-assembly properties for water-dispersed WPET are significantly
reduced, resulting in enhanced stability. In addition, the electrolytes
Na+, Mg2+, and Ca2+ in the solution
can significantly accelerate the aggregation of WPET. This fundamental
research on the self-assembly properties and aggregation behavior
of WPETs can be used to effectively control and improve the stability
of WPET solutions and provide guidance for the prediction of stability
for WPET molecules not yet synthesized.