“…59 Still, a particular focus should be given to the (e) band, related to antisymmetric PO 2 À stretching (B1230 cm À1 ), to the (f) band, arising from the symmetric PO 2 À stretching (B1063 cm À1 ) 60 and to the (g) band, possibly related to the P-N phosphoramide and to dianionic phosphodiester vibrations (B930-966 cm À1 ). 61,62 Furthermore, in a parallel control experiment, GQDs-ED were linked to 5 0 -Phos-DNA only via non-covalent interactions (i.e., without EDC/1-MeIm), and the recorded FTIR spectrum showed differences in comparison to the GQDs-DNA, which may suggest that covalent bonds occur when using the normal experimental conditions (Fig. S8, ESI †).…”