The electric quadrupole moment of the 33 13 Al 20 ground state, located at the border of the island of inversion, was obtained using continuous-beam β-detected nuclear quadrupole resonance (β-NQR). From the measured quadrupole coupling constant ν Q = 2.31(4) MHz in an α-Al 2 O 3 crystal, a precise value for the electric quadrupole moment is extracted: |Q s ( 33 Al)| = 141(3) mb. A comparison with large-scale shell model calculations shows that 33 Al has at least 50% intruder configurations in the ground state wave function, favoring the excitation of two neutrons across the N = 20 shell gap.33 Al therefore clearly marks the gradual transition north of the deformed Na and Mg nuclei towards the normal Z 14 isotopes.