The reactive ion etching of
normalInAs
,
normalInSb
,
normalInP
,
normalInGaAs
, and
normalInAlAs
in
SiCl4/normalAr
or
Cl2/normalAr
discharges was investigated as a function of the plasma parameters power density, pressure, and relative composition as well as etching time. The etch rates of all of these materials with the exception of
normalInP
are faster in
SiCl4/normalAr
in comparison to
Cl2/normalAr
, and show a similar dependence on power density and discharge composition. The variation of etch rates with pressure, however, are quite different for the two gas mixtures, with all of the materials going through a maximum at 60–80 mtorr for
SiCl4/normalAr
, while continuing to show a monotonic increase with pressure for
Cl2/normalAr
. The surface morphologies after RIE with either type of discharge are generally quite rough, although smooth etching can be obtained under appropriate conditions. Increased reverse bias currents are observed in Au/n‐type
normalInP
Schottky diodes after RIE, with higher currents for low pressure or high self‐bias etching. Photoluminescence decreases from
normalInP
are also observed after RIE, ranging in magnitude from 2–10 times. The depth of point defect introduction by energetic ion bombardment is limited to <200Å in
normalInP
for RIE at 50 mtorr and dc biases on the samples of 50V. Chlorine‐containing residues are present typically to a depth of ∼40Å on all of the material after RIE in either type of discharge. The addition of
SF6
to both gas mixtures leads to a high selectivity for
normalInP
and
normalInGaAs
over
normalInAlAs
because of the formation of a thin involatile layer of
AlF3
on the
normalInAlAs
.