2003
DOI: 10.4152/pea.200301015
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Galvanostatic Growth of Passivating Films Under Transient Conditions. I. Model and Quantitative Analysis for the Zn/ZnO System

Abstract: On the basis of an ohmic model and a Tafel equation describing relations between current density and overpotentials in the film and at the metal/film interface, respectively, it is shown that a quantitative analysis of galvanostatic transients for the growth of passivating ultra-thin films on the so-called non-noble metals can be obtained. As an example, the growth of ZnO on Zn in a boric/borate buffer solution is considered. In this case, the values of the transfer coefficient and the exchange current density… Show more

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