Abstract-Hydrodynamic and mass transfer characteristics of an annulus-rising airlift reactor (AR_ALR) were investigated with experimental and CFD simulation methods. An Eulerian model with two bubble phases was developed to simulate the AR_ALR in three circulation flow regimes. 3D steady state CFD simulations were performed under different gas superficial velocities (U g ). Good agreements on gas holdup and volumetric mass transfer coefficient were obtained over the range of the studied U g . The simulated averaged liquid velocities in AR_ALR with different scales were compared and accounted for the influence of reactor scale on gas holdup. The three flow regimes in AR_ALR were captured well and are similar to those observed in experiments. The developed CFD model can be used to predict the hydrodynamics and mass transfer in AR_ALRs with different scales.Index Terms-Annulus-rising airlift reactor, CFD, mass transfer, scale-up effect.
I. INTRODUCTIONAirlift loop reactors (ALRs) have received more and more attention in chemical, petrochemical and biochemical industries. They are used in fermentation, waste water purification, hydrogenation and exhaust-gas treatment [1], [2]. ALRs have some advantages over bubble columns such as enhanced mixing, mass and heat transfer, and suspension of particles with low energy consumption. The mild and constant shear environment in ALRs, contrary to mixing tanks, is preferable for bioprocesses with fragile particles [3].ALRs usually are composed of a riser with a gas feed, and a downcomer where the liquid phase flows downwards. An enlarged expansion, called gas separator, is often placed on the top of the column in order to achieve good separation of gas and liquid phases. Generally, two types of ALRs, an internal-loop airlift reactor (IL-ALR) and an external-loop airlift reactor (EL-ALR), are classified according to the arrangement of the riser and the downcomer. For IL-ALR, two operating modes can be used which are the gas-feeding in the draft tube (center-rising airlift reactor, CR_ALR) and the gas feeding in the annulus (annulus-rising airlift reactor, AR_ALR) modes.A large number of studies on CR_ALRs have been reported and great achievements have been obtained with experimental [4]- [8] AR_ALRs have in fact higher gas holdups and mass transfer rates than CR_ALRs, especially for liquid phase systems which have frothing properties. The anti-frothing ability of the AR_ALRs is higher than CR_ALRs due to much more bubbles being entrained into the downcomer. Moreover, most of the studies, typically in bioprocesses, have been performed in bench-scale (1 -10 L) ALRs [15] and are limited to the specified aeration rates [2]. The yield of desired products may be lower than expected even in pilot-scale applications [19] due to the effects of the reactor scale, aeration and agitation. It is therefore necessary to investigate the effect of aeration and scale on hydrodynamics and mass transfer in AR_ALR so that the performance of the reactor would satisfy the process needs as well as pos...