Gas-phase radiation-chemical oxidation of naphthalene

Nichipor, G. V.; Gerasimov, G. Ya.

doi:10.1134/s0018143908050019

Cited by 1 publication

(1 citation statement)

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“…The qualitative analysis of the products of NL oxidation in the N 2 /O 2 /H 2 O mixture [8] shows that naphthol and nitronaphthalene are the main stable products of the radiolysis, as well as 2,6-diethyl-p-benzoquinone, 2,3-dihydroindene, dimethoxybenzenes, and carbon oxides. The attempt to quantitatively determine the concentrations of NL oxidation products was made in [43], where the detailed kinetic model of the process based on the radical mechanism of the PAHs transformation was proposed. Figure 6 shows calculated concentration curves of the NL decomposition process in the N 2 /O 2 /H 2 O mixture.…”

Section: Resultsmentioning

confidence: 99%

Kinetic Mechanisms of Electron-Beam Induced Polycyclic Aromatic Hydrocarbons Transformation in Flue Gases

Gerasimov

2015

Plasma Chem Plasma Process

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The effect of non-thermal plasma generated by electron-beam on the behavior of polycyclic aromatic hydrocarbons (PAHs) in industrial flue gases was investigated using methods of mathematical modeling. The proposed kinetic model of the process includes mechanism of PAHs conversion caused by their interaction with OH-radicals, ion-molecular mechanism of PAHs decomposition, and ion-molecular mechanism of higher-ringed PAHs formation. The model allows to predict the main features of the process, which are observed in pilot plant installations, and to give quantitative estimations of the process efficiency. The results of calculations are compared with the available experimental data.

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Section: Resultsmentioning

confidence: 99%

Kinetic Mechanisms of Electron-Beam Induced Polycyclic Aromatic Hydrocarbons Transformation in Flue Gases

Gerasimov

2015

Plasma Chem Plasma Process

View full text Add to dashboard Cite

show abstract

Gas-phase radiation-chemical oxidation of naphthalene

Cited by 1 publication

References 25 publications

Kinetic Mechanisms of Electron-Beam Induced Polycyclic Aromatic Hydrocarbons Transformation in Flue Gases

Kinetic Mechanisms of Electron-Beam Induced Polycyclic Aromatic Hydrocarbons Transformation in Flue Gases

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