In this paper, results of hydrogen production from hydrocarbons in the atmospheric pressure microwave plasma are presented. As sources of hydrogen, both methane CH 4 and tetrafluoroethane C 2 H 2 F 4 were tested. A new waveguide-based nozzleless cylindertype microwave plasma source was used to convert hydrocarbons into hydrogen. The processed gaseous hydrocarbons were introduced to the plasma by four gas ducts which per kWh of microwave energy absorbed by the plasma, respectively. These parameters are better than our previous results when nitrogen was used as a swirl gas and much better than those typical for other plasma methods of hydrogen production (electron beam, gliding arc, plasmatron).
The paper presents the theoretical basis and results of numerical modeling of co-rona discharge phenomenon carried out to determine the value of body force that induces the flow of surrounding fluid. The system of two partial differential equations is solved with the values of electric potential ϕ and space charge density ρq as unknowns. The first equation is of Poisson-type with Laplacian acting on the value of potential and source term dependent on space charge density as well as electric permittivity of the medium. The second equation is current continuity equation, where the current density is composed of charge carrier diffusion term and the term describing their drift in electric field. Particular attention was given to the boundary condition of space charge density due to its indirect nature. Geometry of the problem assumes that positive corona discharge takes place on the sharp edge of the blade-shaped anode while flat grounded plate acts as a cathode. Such configuration enables simplified analysis in 2D Cartesian coordinates assuming that the section plane is sufficiently far from the lateral edges of the blade. The system of equations is solved with MOOSE (Multiphysics Object-Oriented Simulation Environment) Framework released in public domain on GNU LGPL license by Idaho National Laboratory. Presented results include 2D distributions of electric potential, electric field strength, space charge density and body force in air surrounding electrodes.
The objective of this work was to explain the efficient NOx removal from simulated flue gas observed in the hybrid corona discharge-catalyst hybrid systems with either V
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