“…Since the discovery of graphene in 2004, a variety of two-dimensional (2D) materials have been experimentally synthesized or theoretically predicted, such as transition metal sulfides, − phosphorene, − and MXenes. , Due to the dangling-bond-free surfaces and atomic thickness, − the 2D materials and their heterojunctions are widely used to design and fabricate multitudinous devices, ,, including diodes, ,− gas sensors, field-effect transistors, ,, etc. Among them, as the diodes are one of the most commonly used electronic components, they have been extensively studied based on both lateral and vertical heterojunctions. ,,, Since the lateral heterojunction diodes are obtained by seamlessly stitching the edges of two different 2D materials in the same plane via chemical bonding, the lattice-constant matching between these two panels is an essential parameter in determining the performance of the diodes, due to its influence on the interfacial properties and the efficiency of carrier injection. − Differently, the vertical heterojunctions are composed of 2D materials by van der Waals interaction, avoiding the misfit dislocations at the interfaces, and thus the requirement of lattice-constant matching is relaxed in the fabrication of vertical heterostructure diodes . However, their stacking orientation is a key issue restricting the performance of vertical heterojunction–based diodes .…”