Rationally designing the core/shell architecture of Pt-based electrocatalysts has been demonstrated as an effective way to induce a surface strain effect for promoting the sluggish kinetics of the oxygen reduction reaction (ORR) at the cathode of fuel cells. However, unstable core dissolution and structural collapse usually occur in Pt-based core/shell catalysts during the long-term cycling operation, greatly impacting actual fuel cell applications. Impeding the dissolution of cores beneath the Pt shells is the key to enhancing the catalytic stability of materials. Herein, a method for sandwiching atomic PdAu interlayers into one-dimensional (1D) Pd/Pt core/shell nanowires (NWs) is developed to greatly boost the catalytic stability of subnanometer Pt shells for ORR. The Pd/PdAu/Pt core/shell/shell NWs display only 7.80% degradation of ORR mass activity over 80 000 potential cycles with no dissolution of Pd cores and good preservation of the holistic sandwich core/shell nanostructures. This is a significant improvement of electrocatalytic stability compared with the Pd/Pt core/shell NWs, which deformed and inactivated over 80 000 potential cycles. The density functional theory (DFT) calculations further demonstrate that the electron-transfer bridge Pd and electron reservoir Au, serving in the PdAu atomic interlayer, both guarantee the preservation of the high electroactivity of surface Pt sites during the long-term ORR stability test. In addition, the Pd/PdAu/Pt NWs show a 1.7-fold higher mass activity (MA) for ORR than the conventional Pd/Pt NWs. The enhanced activity can be attributed to the strong interaction between PdAu interlayers and subnanometer-Pt shells, which suppresses the competitive Pd-4d bands and boosts the surface Pt-5d bands toward the Fermi level for higher electroactivity, proved from DFT.

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Networked teleoperation with haptic feedback is a prime example for the emerging Tactile Internet, which requires a careful orchestration of haptic communication and control. One major challenge in this context is how to maximize the user's quality-of-experience (QoE) while ensuring at the same time the stability of the global control loop in the presence of communication delay. In this paper, we propose a dynamic control scheme switching strategy for teleoperation systems, which maximizes the QoE for time-varying communication delay. In order to validate the feasibility of the proposed approach, we perform a dedicated case study for a virtual teleoperation environment consisting of a one-dimensional spring-damper system, and conduct extensive subjective tests under various delay conditions for two control schemes : (1) teleoperation with the time-domain passivity approach (TDPA), which is highly delay-sensitive but supports highly dynamic interaction between the operator and a potentially quickly changing remote environment; (2) model-mediated teleoperation (MMT), which is tolerable to relatively larger communication delays, but unsuitable for quickly changing, highly dynamic remote environments. For both schemes, we use recently proposed extensions, which incorporate perceptual data reduction to reduce the required packet rate between the operator and the teleoperator. One key contribution of this paper lies in the exploration of the intrinsic relationship among QoE, communication delay and the control schemes which provides a fundamental guidance, not only to this research, but also to the future joint optimization of communication and control for time-delayed teleoperation systems.

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In this paper, a robust DC-link voltage control scheme is proposed to improve the tolerance of photovoltaic (PV) grid-connected inverter to disturbances. The sensitive characteristic of the DC-link voltage complicates the dynamics of the inverter control system and limits its overall performance, especially when uncertain disturbances are considered. To cope with this issue, a voltage controller based on the linear active disturbance rejection control (LADRC) is designed. By exploring the principle of deviation regulation, an improved linear extended state observer (LESO) is established to ensure that the total disturbance can be estimated in a relatively timely manner. The linear state error feedback (LSEF) control law is generated to compensate for the total disturbance, which reduces the plant to approximate the canonical cascaded double integrator. The stability and disturbance rejection capability of the improved LADRC are further analyzed in frequency domain. Finally, theoretical analysis and experimental results confirm the feasibility of the proposed control scheme.INDEX TERMS Photovoltaic (PV) grid-connected inverter, DC-link voltage, linear active disturbance rejection control (LADRC), deviation regulation, total disturbance.