As a common and mature algorithm, the neural network algorithm has been widely used in many industries throughout the country. The traditional dialectical analysis method for multiple intelligences evaluation in comparative education cannot meet the dialectical needs with different characteristics, the information big data model of multiple intelligences evaluation based on neural network algorithm has been gradually applied to several evaluation systems of comparative education. This paper studies the application of neural network algorithms in the dialectical analysis of comparative education in China and puts forward multiple intelligences evaluation model based on neural network algorithm, which can realize the intelligent evaluation of comparative education according to the characteristics of teaching behavior. At the same time, the idea of random big data acquisition is combined with digital feature analysis based on neural network algorithm and particle swarm optimization algorithm. Finally, the experimental results show that the dialectical analysis model of comparative education based on multiple intelligences evaluation of neural network algorithm can efficiently process the education data with tracking intelligence, which achieves a new breakthrough in the multiple intelligences evaluation of comparative education in China and saves a lot of time for the dialectical analysis process.