Generalized equations of the Burnett P-V-T methods for adsorbing gases

A new evaluation of (p, ρ,T) measurements on steam with corrections for the effects of physical and chemical adsorption

“…In addition, it is to be noted that Eubank et al did not consider the parameter a 0 according to equation (22) to be adjustable, but to equal unity in (Z − 1)/r. In a more recent paper, Warowny and Eubank (16) confirmed the experimental results and the ability of their evaluation scheme to derive second virial coefficients of steam.…”

Molecular‐based virial coefficients of CO2‐H2O mixtures

“… Second virial coefficient of H 2 O, B 02 . Experimental data (open symbols) are from Eubank et al, Warowny and Eubank, Kell et al, and Abdulagatov et al Calculated values (filled symbols) from this work are based on the potential of Góra et al with and without semiclassical corrections (as indicated), and the GCPM for H 2 O from Pericaud et al The experimentally based correlation of Harvey and Lemmon is shown with the solid line. Confidence limits are smaller than the symbol sizes for all data, or (for Eubank et al and Warowny‐Eubank) are unknown.…”

“… Third virial coefficient of H 2 O, B 03 . Experimental data (open symbols) are from Eubank et al, Warowny and Eubank, Kell et al, and Abdulagatov et al Calculated values (filled symbols) from this work are based on the potential of Góra et al with and without semiclassical corrections for U 2 (as indicated). Results that include the 3‐body contribution U 3 are indicated, using the generic polarization+dispersion approach (Eqs.…”

CHAPTER 1. Volumetric Properties: Introduction, Concepts and Selected Applications

“…86,[179][180][181] For molecular gases it is not possible to write Equation (1.11) as a Laplace transform, that is a formal inversion procedure does not exist in this case. The majority of virial coefficient data has been obtained by PVT (or PrT) measurements, [182][183][184][185][186][187][188][189][190][191][192][193][194][195][196][197][198] of which the Burnett technique 182-188 is perhaps the most commonly used. For subcritical temperatures, adsorption is a major problem, which has been, however, successfully resolved by Wagner and collaborators [191][192][193][194][195] by introducing a new compensation method based on Archimedes' buoyancy principle: two sinkers of identical mass and surface area but significantly different volumes were used.…”