Dedicated to Professor R. Gorenflo on the occasion of his 80th birthdayA connection between fractional calculus and statistical distribution theory has been established by the authors recently. Some extensions of the results to matrix-variate functions were also considered. In the present article, more results on matrix-variate statistical densities and their connections to fractional calculus will be established. When considering solutions of fractional differential equations, Mittag-Leffler functions and Fox Hfunction appear naturally. Some results connected with generalized MittagLeffler density and their asymptotic behavior will be considered. Reference is made to applications in physics, particularly superstatistics and nonextensive statistical mechanics.MSC 2010 : 15A15, 15A52, 33C60, 33E12, 44A20, 62E15