The
hydrazone organics have obvious third-order nonlinear optical
properties because of the existence of the delocalized π-electrons
and the strong coupling between electrons with geometric structure.
Compared with traditional inorganic materials, hyrazone materials
have the advantages of fast response time, low dielectric constant,
convenient preparation, and strong delocalization electronic system.
However, the strength of this material in nonlinear optics and ultrafast
photonics is rarely involved. In this article, we studied the optical
energy gap through the density functional theory (DFT) method to verify
the nonlinear absorption characteristics of hydrazone compound 1-(anthracen-9-ylmethylene)-2-(perfluorophenyl)hydrazine
(Ayph). The nonlinear transmission characteristics of Ayph are studied
with high modulation depth of ∼7.46% and saturation absorption
intensity of ∼49.37 MW·cm–2. Most importantly,
by adding Ayph saturable absorber to the Er-doped fiber laser, we
are able to generate ultrashort pulses with very stable operation
at a central wavelength of 1563.9 nm first. The preparation and characterization
of Ayph and other characteristics of traditional soliton pulse are
also discussed. It has been proved that Ayph is a promising material
for ultrafast broadband nonlinear optics for the first time to our
knowledge. Considering the material’s rich characteristics
and structural controllability, these studies lay the foundation for
multifeature photonics.