Generation of the active Pd cluster catalyst in the Suzuki–Miyaura reactions: Effect of the activation with H2 studied by means of quick XAFS

The roles of metal co-catalysts and reaction media in photocatalytic hydrogen production: Performance evaluation of M/TiO2 photocatalysts (M = Pd, Pt, Au) in different alcohol–water mixtures

“…The data for the Pd/TiO 2 photocatalyst were qualitatively similar to those collected for a 5 lm thick Pd metal reference foil, whereas the data for the Pd/TiO 2 photocatalyst precursor (i.e. PdO/TiO 2 ) closely resembled those collected for PdO [34]. Pd 3d XPS analysis on the 1 wt.% Pd/TiO 2 sample (Fig.…”

Direct palladium/copper oxidative cross-coupling of α-methylstyrene with acrylates

“…Under identical conditions, the Herrmann palladacycle did not exhibited activities (Table 1, entry 11), while 9% and 28% yields were achieved with [12] and PdCl 2 , respectively (Table1, entries 8 and 9).…”

Synthesis of Pd/SiO2 Nanobeads for Use in Suzuki Coupling Reactions by Reverse Micelle Sol–gel Process

“…The Pd(II) complexes/SiO 2 beads were calcined at 773 K for 4 h under hydrogen atmosphere. By heat treatment under a hydrogen flow, the Pd ammine chloride hydrate complex in the silica matrix was reduced [19], and this led to the formation of tiny Pd clusters. The TEM image in Fig.…”