Abstract.A funnel-shaped alteration pipe in Archean rhyolite and andesite below massive sulphide Zn-Cu ores at the Norbec mine in northwestern Quebec was outlined from drill core samples, geochemical parameters, and normative alteration mineralogy. The pipe has a mass of 37.9 million tonnes giving a volume of 13 x 106 m 3, which represents volume increase of 10% relative to the unaltered host volcanic rocks. A bulk chemical composition was calculated using "weighting" procedures for "volumes of influence" for the samples. Net mobile mass change, or chemical flux, for the alteration pipe was + 5.8 x 10 6 tonnes; inclusion of the massive ore lens yields a flux of + 9.6 • 10 6 tonnes for the whole hydrothermal system. The largest additions to the system in millions of tonnes were: FeO(+ 4.2), SiO2(+ 3.8), S(+ 1.8), K20(+0.55), and MgO(+ 0.5); the only depletions were Na20 ( -1.4), and CAO(-0.44). Base and precious metals accounted for 3.4% of the total element flux.Alteration zones below volcanogenic massive sulphide deposits commonly are confined to pipe-shaped volumes of rock that have been subjected to intense hydrothermal fluid flow. The fluids exited onto paleo-seafloors as metalbearing hot springs to form conformable lenses of massive sulphide ore (Franklin et al. 1981;Lydon 1984Lydon , 1988. The alteration pipes commonly expand upwards into funnelshaped outlines near the rock-seawater interface. The altered rocks have undergone major chemical and mineralogical changes, and many components have been leached while others were deposited. The bulk chemical compositions of alteration pipes have not been well documented, nor have the input and output of chemical components (the chemical flux) during the ore forming process been measured. It is now possible to measure these changes using elements that can be shown to be immobile in the system, and by applying the techniques developed by MacLean and Kranidiotis (1987) and MacLean (1990).