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Штильман, М.И.; Tsatsakis, Aristidis; Alegakis, Athanasios; Voskanyan, P. S.; Shashkova, I. M.; Rizos, Apostolos K.; Krambovitis, Elias

doi:10.1023/a:1020673004933

Cited by 8 publications

(5 citation statements)

References 5 publications

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“…(2-Naphthylthio)acetic acid (molecular formula: C 12 H 10 O 2 S, CAS Registry No. 93-21-0, molecular weight: 218.27 g·mol –1 , IUPAC name: 2-naphthalen-2-ylsulfanylacetic acid, structural formula is shown in Figure S1 of the Supporting Information) is an important synthetic insecticide, which shows the characteristics of high efficiency, low toxicity, broad spectrum, herbicidal activity, and biodegradability, used to control mites in fruit trees, cotton, and vegetables. − The selective acaricides named tetradifon and kelthane have been widely used all over the world. In particular, a novel insecticide combination of acaricidal sulfone trichloride, propargite, diafenthiuron, or derivatives thereof enhances greening and yield increase of crops to which it is applied and late-aging the crops, thereby increasing the yield of the crops, reducing the pest stress in the crops to which it is applied, and enhancing the pesticidal activity and protection of plants from attack or infestation by insects, mites, or nematodes. , …”

Section: Introductionmentioning

confidence: 99%

Equilibrium Solubility and Mathematical Correlation of (2-Naphthylthio)acetic Acid in Four Aqueous Cosolvency Systems at 278.15–323.15 K

Zhang

2021

J. Chem. Eng. Data

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Pure solvents are often single in nature and often cannot meet the dissolution requirements of (2-naphthylthio)acetic acid. The method of adding a solvent into another solvent to form a mixed solvent improves this situation. As a common solvent, water cannot dissolve the solute in this study well, so methanol was added into water to form a liquid mixture of different compositions. At first, the ratio of methanol mass is 90% and then decreases by 10% until the methanol content is 10%. According to the above method, ethanol, isopropanol, and N,Ndimethylformamide (DMF) are made into corresponding mixed solvents. Under a pressure of 101.2 kPa, the temperature of (2-naphthylthio)acetic acid and the solvent is kept at 278.15 K. Based on the basic principle of the static gravimetric method, the amount of solute diffusion in the above four mixed solvents is obtained. Other conditions remain unchanged, but the temperature increases by 5 K and the above steps are repeated until the temperature is 323.15 K. Generally speaking, there are two variables in the experiment, one is the temperature variable and the other is the organic solvent ratio variable. Other variables remain the same, but the temperature changes to a higher level, and more (2-naphthylthio)acetic acid can be detected in the solution. Regardless of the change in the temperature variable, the larger the mass of the organic solvent, the more the solute in the solution. The above rules are applicable to the four groups of mixed solvents, but under the same conditions, the combination of DMF and water is superior in terms of dissolution. The Jouyban−Acree model, van't Hoff−Jouyban−Acree model, and modified Apelblat−Jouyban−Acree model were employed to correlate the obtained solubility. In all models, the relative average deviation (RAD) and root-mean-square deviation (RMSD) were not more than 5.30% and 6.40 × 10 −5 , respectively. The poor water solubility not only makes the (2-naphthylthio)acetic acid production process more difficult but also suffers many limitations in application because it cannot be prepared into a liquid dosage form and is inconvenient to use on many occasions.

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Section: Introductionmentioning

confidence: 99%

Equilibrium Solubility and Mathematical Correlation of (2-Naphthylthio)acetic Acid in Four Aqueous Cosolvency Systems at 278.15–323.15 K

Zhang

2021

J. Chem. Eng. Data

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“…NAA was loaded in a matrix of an inorganic Zn–Al‐layered double‐hydroxide using a self‐assembly technique, and the mechanism of controlled release was interpreted on the basis of the ion‐exchange process between the NAA anions intercalated in the lamellar host and nitrate/hydroxyl anions in the aqueous solution 9. However, the mechanism of hydrolysis of esters of NAA for its sustained release has drawn more attention because the polymeric derivatives are biologically active after releasing NAA by hydrolysis, and their effectiveness is longer than that of NAA 8–13. The sustained‐release periods of NAA esters ranged from months to years, depending on the types and structures of the copolymers 9–12…”

Section: Introductionmentioning

confidence: 99%

“…The preparation of polymeric esters of NAA derived from epoxy‐bearing random copolymers requires harsh conditions with temperatures higher than 140°C 14. Halogenated polymers were used in other studies to synthesize polyesters of NAA,13, 15, 16 but they were impractical because of their relatively high price and environmental issues related to the presence of halogens. Hydroxy‐bearing polymers are the ideal reagents for synthesizing esters of NAA, such as hexyl isomer alcohols,10 modified amylase,11 poly(ether‐amide)s bearing hydroxyl side groups,12 and poly(vinyl alcohol) 13.…”

Section: Introductionmentioning

confidence: 99%

“…Halogenated polymers were used in other studies to synthesize polyesters of NAA,13, 15, 16 but they were impractical because of their relatively high price and environmental issues related to the presence of halogens. Hydroxy‐bearing polymers are the ideal reagents for synthesizing esters of NAA, such as hexyl isomer alcohols,10 modified amylase,11 poly(ether‐amide)s bearing hydroxyl side groups,12 and poly(vinyl alcohol) 13. In our previous work, modified chitosan was used to prepare a novel formulation for sustained release of NAA,17 but the previous studies were limited to NAA‐releasing behaviors.…”

Section: Introductionmentioning

confidence: 99%

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1‐naphthylacetic‐acid‐functionalized polyacrylate‐coated urea with dual controlled‐release properties

Qiu

Zhu

Tao

et al. 2012

J of Applied Polymer Sci

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Esters derived from 1‐naphthylacetic acid (NAA) and polyacrylate were synthesized and a dual controlled‐release formulation was developed by coating fertilizers with these esters. FT‐IR, 1H NMR, TGA, and DSC were used to characterize the synthesized polymers, and the mechanical properties were also tested. Urea granules were coated with NAA esters, and the release rates of urea from the coated granules in water were measured. NAA release from the esters was performed in different buffer solutions and in soil. The results showed that the coated fertilizers were able to release urea in a controlled pattern and that NAA could be slowly released from membranes of the esters in both buffer solutions and in soil through hydrolysis. The coated fertilizer's availability could last more than 28 days and that of NAA could last more than 12 months, which suggested that the prepared CRF possessed dual controlled‐release of urea and NAA. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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“…This database will be used to develop a conceptual use model for testing biomass materials to estimate biomass performance in harvesting, handling, and processing systems. It is recognized that environmental conditions (i.e., temperature, humidity), stages of maturation, matrix composition, and cell matrix configuration are important test parameters to consider (16,17,18,19,20,21,22). For purposes of simplicity, this study primarily focuses on matrix composition and cell configuration in mature plant biomass for the determination of biomechanical properties.…”

Section: Introductionmentioning

confidence: 99%

Biomechanics of wheat/barley straw and corn stover

Wright

Pryfogle

Stevens

et al. 2005

Appl Biochem Biotechnol

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The lack of understanding of the mechanical characteristics of cellulosic feedstocks is a limiting factor in economically collecting and processing crop residues, primarily wheat and barley stems and corn stover. Several testing methods, including compression, tension, and bend have been investigated to increase our understanding of the biomechanical behavior of cellulosic feedstocks. Biomechanical data from these tests can provide required input to numerical models and help advance harvesting, handling, and processing techniques. In addition, integrating the models with the complete data set from this study can identify potential tools for manipulating the biomechanical properties of plant varieties in such a manner as to optimize their physical characteristics to produce higher value biomass and more energy efficient harvesting practices.

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Cited by 8 publications

References 5 publications

Equilibrium Solubility and Mathematical Correlation of (2-Naphthylthio)acetic Acid in Four Aqueous Cosolvency Systems at 278.15–323.15 K

Equilibrium Solubility and Mathematical Correlation of (2-Naphthylthio)acetic Acid in Four Aqueous Cosolvency Systems at 278.15–323.15 K

1‐naphthylacetic‐acid‐functionalized polyacrylate‐coated urea with dual controlled‐release properties

Biomechanics of wheat/barley straw and corn stover

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