Gold(I) Complexes [N{(C3F7)C(Dipp)N}2]AuL (L = Ethylene, tert‐Butyl Isocyanide, Tetrahydrothiophene, Triphenylphosphine) and Different Triazapentadienyl Ligand Coordination Modes

Hexadentate bis(amidines) form versatile networks of hydrogen bonds both in solid state and solution, as revealed by X-ray crystallography, IR, and NMR spectroscopy. Moreover, the corresponding bis(amidinates) produce blue and green emissions in THF solution. Tethered tetradentate bis(amidines) have emerged in coordination chemistry, enantioselective catalysis, as building blocks for polyfunctional heterocycles, and in photoluminescent materials. The next generation of flexible bis(amidine)/bis(amidinate) platforms with up to six N-donor sites has now been established.

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Ethylene-Bridged Hexadentate Bis(amidines) and Bis(amidinates) with Variable Binding Sites

O’Dea

Trejo

Arras

et al. 2019

J. Org. Chem.

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Gold(I) Complexes [N{(C₃F₇)C(Dipp)N}₂]AuL (L = Ethylene, tert‐Butyl Isocyanide, Tetrahydrothiophene, Triphenylphosphine) and Different Triazapentadienyl Ligand Coordination Modes

Abstract: Fluorinated 1,3,5-triazapentadienyl ligand [N{(C 3

Cited by 1 publication

References 65 publications

Ethylene-Bridged Hexadentate Bis(amidines) and Bis(amidinates) with Variable Binding Sites

Ethylene-Bridged Hexadentate Bis(amidines) and Bis(amidinates) with Variable Binding Sites

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