2021
DOI: 10.1109/jeds.2021.3058631
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Graded Crystalline HfO₂ Gate Dielectric Layer for High-k/Ge MOS Gate Stack

Abstract: Germanium (Ge) has gained great attention not only for future nanoelectronics but for back-end of line (BEOL) compatible monolithic three-dimensional (M3D) integration recently. For high performance and low power devices, various high-k oxide/Ge gate stacks including ferroelectric oxides have been investigated. Here, we demonstrate atomic layer deposited (ALD) polycrystalline (p-) HfO2/GeOX/Ge stack with an amorphous (a-) HfO2 capping layer. The consecutively deposited a-HfO2 capping layer improves hysteretic … Show more

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Cited by 7 publications
(4 citation statements)
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“…The V BI (−0.26 V) was calculated from the 1/C 2 curve (Figure S4a, Supporting Information), while the interface trap density (10 14 cm −2 eV −1 ) was estimated from the variablefrequency C-V characterization (Figure S4b, Supporting Information), which is higher compared to SiO 2 /Si interface. [47][48][49][50] This can be attributed to a large lattice mismatch between the Si and HfO 2 , generating the abundance of uncompensated dangling bonds at the HfO 2 /Si interface during the growth of the HfO 2 layer. They can also act as charge pockets for the photogenerated charge carriers inside the Si depletion region.…”
Section: Resultsmentioning
confidence: 99%
“…The V BI (−0.26 V) was calculated from the 1/C 2 curve (Figure S4a, Supporting Information), while the interface trap density (10 14 cm −2 eV −1 ) was estimated from the variablefrequency C-V characterization (Figure S4b, Supporting Information), which is higher compared to SiO 2 /Si interface. [47][48][49][50] This can be attributed to a large lattice mismatch between the Si and HfO 2 , generating the abundance of uncompensated dangling bonds at the HfO 2 /Si interface during the growth of the HfO 2 layer. They can also act as charge pockets for the photogenerated charge carriers inside the Si depletion region.…”
Section: Resultsmentioning
confidence: 99%
“…As a result, the temperature had to be raised above normal ohmic contact annealing temperature (850 • C). To minimize the gate leakage through the grain boundary between the crystallized HfO 2 , a 30 nm thick amorphous HfO 2 dielectric layer was deposited under the same ALD condition [15,16]. Finally, Ni/Au (20/50 nm) contact was formed on the gate dielectric.…”
Section: Methodsmentioning
confidence: 99%
“…In this regard, strained silicon, III-V materials, and germanium (Ge) are suggested as the future channel material as these provide higher electron mobility compared to silicon. [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31] Out of these non-silicon materials, Ge graves the highest attention of device researchers due to its exceptionally high hole mobility. [17][18][19][20][21] As the current technology deals with CMOS architecture, we need both NMOS and PMOS to be implemented.…”
mentioning
confidence: 99%
“…[17][18][19][20][21][22][23][24][25][26][27][28][29][30][31] Out of these non-silicon materials, Ge graves the highest attention of device researchers due to its exceptionally high hole mobility. [17][18][19][20][21] As the current technology deals with CMOS architecture, we need both NMOS and PMOS to be implemented. Also, a comparable performance between NMOS and PMOS devices is necessary for the precise operation of circuits.…”
mentioning
confidence: 99%