“…Currently, hard anti-wear coatings, mainly multi-layer, composed of nitrides, carbides, oxides and borides of transition metals Ti, Cr, Zr, W, Mo, V, Ta, Nb, Hf [ 1 ] are widely deposited by Physical Vapour Deposition (PVD) on, among others, parts of the machines and mechanisms as well as cutting and forming tools for metal and wood [ 2 , 3 , 4 ]. However, the complexity of the structure and composition of multilayer coatings causes problems primarily related to the mutual adhesion of the individual layers.…”