Semiconductive hydrogels denote a strategically valuable platform associated with interdiscipline fields by double advantages of metals and organisms (ecoâfriendliness, structural flexibility, mixed conduction, realâtime responsiveness, scalable fabrication, and chemical stability). Nevertheless, the orthodox chemical/physical methods processing hydrogels yield planarâlike layers or rough structures without ultrafine feature size or manipulative performance, falling short of ”ârobotics, ”âelectronics, or nâenergy industries. Thereby, scaling the device's volume down and unleashing material's potential become crucially important for broadband applications. A femtosecond laser liftingâoff technique is synthesized with selfâassembly to break conventional volume/resolution limitation, enlarge the geometryâdesign capacity, and desirable electricity conduction for micro/nanosituations. Lowâdimensional highâperformance nanowires, electric circuits, ultrathin interdigital capacitors, manipulative photon filters, and metasurfaces are functionalized here. The repeated experiment concludes a highâdensity integration ability with a subminiature size down to 10 Ă 10 Ă 0.02 ”m3, tunable electric conductivity up to 1.17 Ă 105 S mâ1, and areal capacitance >16.2 mF cmâ2 for energy storage higher than those electrochemical doubleâlayer ones. Large geometry capacity with nanometric resolution provides access to futureâperspective optoelectronic products, nâenergy, bioneural recordings, or interfaces of embedding conditions.