Graphene leading to high surface-to-volume ratio and outstanding conductivity is applied for gas molecule sensing with fully utilizing its unique transparent and flexible functionalities which cannot be expected from solid-state gas sensors. In order to attain a fast response and rapid recovering time, the flexible sensors also require integrated flexible and transparent heaters. Here, large-scale flexible and transparent gas molecule sensor devices, integrated with a graphene sensing channel and a graphene transparent heater for fast recovering operation, are demonstrated. This combined all-graphene device structure enables an overall device optical transmittance that exceeds 90% and reliable sensing performance with a bending strain of less than 1.4%. In particular, it is possible to classify the fast (≈14 s) and slow (≈95 s) response due to sp(2) -carbon bonding and disorders on graphene and the self-integrated graphene heater leads to the rapid recovery (≈11 s) of a 2 cm × 2 cm sized sensor with reproducible sensing cycles, including full recovery steps without significant signal degradation under exposure to NO2 gas.
We present a simple theoretical model to study the effect of a substrate on the resonance of an aperture in a thin metal film. The transmitted energy through an aperture is shown to be governed by the coupling of aperture waveguide mode to the incoming and the outgoing electromagnetic waves into the substrate region. Aperture resonance in the energy transmission thus depends critically on the refractive index of a substrate. We explain the substrate effect on aperture resonance in terms of destructive interference among evanescent modes or impedance mismatch. Our model shows an excellent agreement with a rigorous FDTD calculation and is consistent with previous experimental observations.
We study the scattering properties of an optical slot antenna formed from a narrow rectangular hole in a metal film. We show that slot antennas can be modeled as bound charge oscillators mediating resonant light scattering. A simple closed-form expression for the scattering spectrum of a slot antenna is obtained that reveals the nature of a bound charge oscillator and also the effect of a substrate. We find that the spectral width of scattering resonance is dominated by a radiative damping caused by the Abraham-Lorentz force acting on a bound charge. The bound charge oscillator model provides not only an intuitive physical picture for the scattering of an optical slot antenna but also reasonable numerical agreements with rigorous calculations using the finite-difference time-domain method.
Nanophotonics capable of directing radiation or enhancing quantum-emitter transition rates rely on plasmonic nanoantennas. We present here a novel Babinet-inverted magnetic-dipole-fed multislot optical Yagi-Uda antenna that exhibits highly unidirectional radiation to free space, achieved by engineering the relative phase of the interacting surface plasmon polaritons between the slot elements. The unique features of this nanoantenna can be harnessed for realizing energy transfer from one waveguide to another by working as a future "optical via".
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