Diamond like carbon coatings were manufactured by dual frequency plasma enhanced chemical vapour deposition method on a poly(ether‐ether‐ketone) substrates. In the presented work, modified surfaces were characterized in terms of the tribological parameters, surface topography, mechanical properties and the chemical composition. Obtained results of the research indicate that the highest resistance against wear, which means the most probable application abilities, presented the carbon coatings created in RF plasma with the use of nitrogen for the preliminary stage of preparation. Due to that modification, it was possible to limit the coefficient of friction from the value of c.a. 0.4–0.26 and 35 times decrease the specific wear rate. The DLC coatings deposited in RF plasma exhibited hardness of about 2 GPa with a relatively low contribution of sp3 phase and surface roughness.