Green Binder Based on Enzymatically Polymerized Eucalypt Kraft Lignin for Fiberboard Manufacturing: A Preliminary Study

Abstract

The capability of laccase from Myceliophthora thermophila to drive oxidative polymerization of Eucalyptus globulus Kraft lignin (KL) was studied as a previous step before applying this biotechnological approach for the manufacturing of medium-density fiberboards (MDF) at a pilot scale. This method, which improves the self-bonding capacity of wood fibers by lignin enzymatic cross-linking, mimics the natural process of lignification in living plants and trees. An interesting pathway to promote these interactions could be the addition of lignin to the system. The characterization of E. globulus KL after enzymatic treatment showed a decrease of phenolic groups as well as the aromatic protons without loss of aromaticity. There was also an extensive oxidative polymerization of the biomolecule. In the manufacture of self-bonded MDF, the synergy generated by the added lignin and laccase provided promising results. Thus, whenever laccase was present in the treatment, MDF showed an increase in mechanical and dimensional stability for increasing amounts of lignin. In a pilot scale, this method produced MDF that meets the requirements of the European standards for both thickness swell (TS) and internal bonding (IB) for indoor applications.

Acylation of Lignin with Different Acylating Agents by Mechanical Activation-Assisted Solid Phase Synthesis: Preparation and Properties

“…For the 1 H NMR spectrum of original lignin, the peaks at 6–8, 3–3.5, 3.5–4, 8–10, and 1.7 ppm corresponding to the aromatic ring skeleton, aliphatic hydroxyl, methoxy, phenolic hydroxyl, and alkyl groups respectively, were distinguishable, which were typical characteristics of lignin [35]. The changes of the peaks at 1.5–2.6 ppm corresponding to alky groups were obvious after esterification, except maleylation.…”

Polymers from Bamboo Extracts Produced by Laccase

“…The concept of the cohesion of the lignin phenolic hydroxyl groups has been established by several authors including Felby et al [6,37]. The use of lignin-oxidizing enzymes for bonding applications is inspired by the reactivity of phenoxy radicals in the plant cell wall.…”

Thinking Green: Sustainable Polymers from Renewable Resources

“…Biodegradable poly(ε-caprolactone) blends with ionic liquid are studied in regard to their crystallization characteristics [34]. Furthermore, the use of a green binder based on enzymatically polymerized eucalypt kraft lignin for fiberboard applications is tested [35].…”