The lead-free Ca(Sn
x
Ti1–x
)O3, (0 ≤ x ≤
0.8) sample has been successfully prepared through the ball milling
process, sintered at 1200 °C for 3 h. The structural, morphological,
vibrational, and microwave dielectric properties of synthesized samples
were analyzed by X-ray diffraction (XRD), scanning electron microscopy
(SEM), Fourier transform infrared spectroscopy (FT-IR), and impedance
analysis. All the samples have an orthorhombic phase structure with
a space group of Pbnm formation, and the crystalline
size and strain changes with respect to Sn4+ doping were
observed in the XRD analysis. From a morphological point of view,
on increasing the content “x”, the
grain size reduces from 3.29 to 1.37 μm. The existence of vibrations
and the bridging stretching mode of Ti–O–Ti and Ti–O–Sn
both are associated with the broadband in the region below 800 cm–1 verified by FT-IR. The variation in electrons hopping
off the host compound with respect to Sn4+ ions was analyzed
in AC conductivity. The changes of dielectric properties such as complex
permittivity, modulus spectroscopy, and dielectric loss at room temperature
with a different frequency range of 1.00–2.00 GHz are discussed.