Present report concerns fabrication of nanostructured TiO 2 -based p-n homojunction, by the hybrid technique involving deposition of sol-gel grown not intentionally doped p-type TiO 2 nanoparticle layer over the electrochemically grown aligned, n-type TiO 2 nanotube array. The Au/ p-TiO 2 / n-TiO 2 nanotube/Ti device was found to offer the ideality factor and the cut-in voltage of ∼4 and ∼1.2 V, respectively, in the temperature range of 30°C-80°C. The structural advantages of TiO 2 nanotubes, owing to the large junction area, eventually offered attractive rectifying behavior (∼10 3 orders) of the fabricated junction.Index Terms-Sol-gel p-TiO 2 , electrochemical n-TiO 2 nanotubes, p-n homojunction, high rectification, low ideality factor.