2005
DOI: 10.1016/j.jcrysgro.2004.11.119
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Growth and spectroscopic investigation of ytterbium-doped NaLa(WO4)2 single crystals

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Cited by 30 publications
(21 citation statements)
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“…Up to this doping level micrometer-size bubbles occasionally appear locally but for higher levels the density of these defects increases with Yb concentration. The tetragonal structure was confirmed by X-ray diffraction and it was established that the Yb incorporation leads to reduction of the unit cell parameters a and Due to the quasi-three-level operation of ytterbium lasers a large enough crystal field splitting of the 2 [6] for low Yb-doping levels amounts to 220 µs.…”
Section: Crystal Preparation and Optical Host Propertiesmentioning
confidence: 92%
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“…Up to this doping level micrometer-size bubbles occasionally appear locally but for higher levels the density of these defects increases with Yb concentration. The tetragonal structure was confirmed by X-ray diffraction and it was established that the Yb incorporation leads to reduction of the unit cell parameters a and Due to the quasi-three-level operation of ytterbium lasers a large enough crystal field splitting of the 2 [6] for low Yb-doping levels amounts to 220 µs.…”
Section: Crystal Preparation and Optical Host Propertiesmentioning
confidence: 92%
“…Details of the crystal growth can be found elsewhere [6]. Transparent samples were obtained for ytterbium concentrations up to 4 wt% (15.4 mol%) in the melt.…”
Section: Crystal Preparation and Optical Host Propertiesmentioning
confidence: 99%
“…The synthesis process was realized through solid state reaction as described in the literature by Serrano et al [11] which is summarized as follows.…”
Section: Methodsmentioning
confidence: 99%
“…De fato, a hipótese de que a taxa de puxamento das fibras decresça quanto maior for a diferença de raios iônicos entre os constituintes metal alcalino e terra rara é consistente com os resultados experimentais observados para a taxa de puxamento, conforme descrito na Tabela 6-1, e com a discussão acima. [37,59] 0,02-0,04 [180] No caso do NLW, como o Na e o La possuem raios iônicos similares, espera-se uma mobilidade cooperativa entre ambos durante sua incorporação na interface de crescimento. Entretanto, para o Li e o La no caso do LLW, a diferença de raios iônicos é tão significante que induz a uma molibidade competitiva, onde a diminuição da taxa de puxamento durante o crescimento das fibras é necessária para permitir a adição destes átomos nos sítios mais prováveis na interface de crescimento.…”
Section: Crescimento E Caracterização De Fibras Monocristalinasunclassified
“…Na Tabela 6-1 são listadas as taxas de puxamento utilizadas no crescimento de fibras monocristalinas de NLW [59] e LLW [38], bem como para o crescimento dos mesmos cristais pela técnica CZ [180] e [26,36], respectivamente. Analisando-se as propriedades estruturais descritas nos trabalhos acima e as taxas de puxamento empíricas utilizadas no crescimento dos cristais de NLW, LLW, Eu:LLW e LEW, consideramos a hipótese de que quanto maior for a diferença (efetiva) entre os cátions (de acordo com a equação (6-1), menor será a taxa de puxamento aplicada durante o processo de crescimento destes tungstatos duplos.…”
Section: Crescimento E Caracterização De Fibras Monocristalinasunclassified