H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides

Rasooli, Mohsen; Zolfigol, Mohammad Ali; Moslemin, Mohammad Ali; Mohebat, Razieh; Chehardoli, Gholamabbas

doi:10.33945/sami/ecc.2020.1.5

Cited by 1 publication

(1 citation statement)

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“…Accordingly, due to the fact that organic tribromides are able to release a stoichiometric amount of bromine, stable, and crystalline solids, they have received great attention in organic synthesis. [88,89] Over the past few years, many improved methods of organic ammonium ditribromides synthesis, as a brominating catalyst, have been reported, involving the oxidation of Br − to Br 3 − in efficient and environmentally benign manner. In this regard, In 2014, Dhar et al…”

Section: Trihalide Reagents Catalyzed the Silylation Of Hydroxyl Grmentioning

confidence: 99%

Recent advances in catalytic silylation of hydroxyl‐bearing compounds: A green technique for protection of alcohols using Si–O bond formations

Ashraf

Liu

et al. 2020

Applied Organom Chemis

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The development of catalytic silylation of alcohols under ambient reaction conditions plays an important role in organic synthesis. New silyl groups and methods for their introduction and removal are constantly being developed and offer chemists a wider range of options. In recent years, silyl protecting groups have been given expanded roles beyond their traditional use of temporarily rendering inactive alcohols. As silyl ether can be further converted to the parent alcohols in acidic conditions, silylation of alcohols can be regarded as an alternative method for hydroxyl protection under ambient reaction conditions. Merging the silyl protection/deprotection of alcohols with such modern methodologies, as green chemistry and nanoscience, has added additional value to these temporary components of synthetic intermediates. This review describes the historical background of the trimethylsilyl ethers preparation from alcohols using catalytic complexes and also the transformation of trimethylsilyl ethers into alcohol-containing compounds via deprecation techniques.

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Section: Trihalide Reagents Catalyzed the Silylation Of Hydroxyl Grmentioning

confidence: 99%

Recent advances in catalytic silylation of hydroxyl‐bearing compounds: A green technique for protection of alcohols using Si–O bond formations

Ashraf

Liu

et al. 2020

Applied Organom Chemis

View full text Add to dashboard Cite

show abstract

H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides

Abstract: Eurasian Chemical Communications H2O2 as a green and environmentally benign reagent for the oxidation of sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides

Cited by 1 publication

References 20 publications

Recent advances in catalytic silylation of hydroxyl‐bearing compounds: A green technique for protection of alcohols using Si–O bond formations

Recent advances in catalytic silylation of hydroxyl‐bearing compounds: A green technique for protection of alcohols using Si–O bond formations

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