We report the structure, magnetic property and spin polarization of CoFeMnGe equiatomic quaternary Heusler alloy. The alloy was found to exist in the L2 1 structure with considerable amount of DO 3 disorder. Thermal analysis result indicated the Curie temperature is about 711K without any other phase transformation up to melting temperature. The magnetization value was close to that predicted by the Slater-Pauling curve. Current spin polarization of P = 0.70 ± 0.1 was deduced using point contact Andreev reflection (PCAR) measurements. Halfmetallic trend in the resistivity has also been observed in the temperature range of 5 K to 300 K. Considering the high spin polarization and Curie temperature, this material appears to be promising for spintronic applications.Key words: Heusler alloy, Mössbauer spectroscopy, Slater-Pauling rule, Spin Polarization, Half-metal. PACS: 75.50.Bp, 75.30.Cr, 75.47.Np, 76.80.+y, 75.76 The polycrystalline bulk sample of an equiatomic CoFeMnGe (CFMG) alloy was prepared by arc melting of stoichiometric quantities of constituent elements in an inert atmosphere. The ingot was melted several times to increase the chemical homogeneity and the final weight loss was less than 1%. To increase the homogeneity, the as-cast alloy was annealed under vacuum for 14 days at 1073 K and then quenched in cold water. The crystal structure was investigated by x-ray diffraction with Cu K α radiation at room temperature. 57 FeMössbauer spectra at room temperature were recorded using a constant acceleration spectrometer with 25 mCi 57 Co(Rh) radioactive source. The spectrometer was calibrated by using natural iron foil of 25 µm before measuring the sample. The obtained spectra were analyzed using PCMOS-II least-squares fitting program. Curie temperature and the structural transition temperature (if any) were probed by using the differential thermal analysis (DTA)with a heating rate of 20 K min -1 . Magnetization measurements at 3 K and 300 K were performed by using a vibrating sample magnetometer (VSM) attached to a physical property measurement system (PPMS, Quantum design). Current spin polarization measurements were done by using the point contact Andreev reflection (PCAR) technique. 19 Sharp Nb tips prepared by electrochemical polishing were used to make point contacts with the sample.Spin polarization of the conduction electrons was obtained by fitting the normalized conductance G(V)/G n curves to the modified Blonder-Tinkham-Klapwijk (BTK) model. 20 A multiple parameter least squares fitting was carried out to deduce spin polarization (P) using dimensionless interfacial scattering parameter (Z), superconducting band gap (∆) and P as variables. Fig. 1 shows the Rietveld refinement of powder XRD pattern recorded at room temperature. The lattice parameter of the alloy was found to be 5.75 Å, which is in agreement with the earlier reports on CFMG. 14 As one can see, superlattice reflections, (111) and (200), are very weak for this alloy. When Z element is from the same period of the periodic system...