Atomic decomposition plays an important role in establishing the boundedness of operators on function spaces. Let 0 < , < ∞ and = ( 1 , 2 ) ∈ ℝ 2 . In this paper, we introduce multi-parameter Triebel-Lizorkin spaceṡ , (ℝ ) associated with di erent homogeneities arising from the composition of two singular integral operators whose weak (1, 1) boundedness was rst studied by Phong and Stein [32]. We then establish its atomic decomposition which is substantially di erent from that for the classical one-parameter Triebel-Lizorkin spaces. As an application of our atomic decomposition, we obtain the necessary and su cient conditions for the boundedness of an operator on the multi-parameter Triebel-Lizorkin type spaces. In the special case of 1 = 2 = 0, = 2 and 0 < ≤ 1, our spaceṡ , (ℝ ) coincide with the Hardy spaces com associated with the composition of two di erent singular integrals (see [19]). Therefore, our results also give an atomic decomposition of com . Our work appears to be the rst result of atomic decomposition in the Triebel-Lizorkin spaces in the multi-parameter setting.