In this paper we explore the role of muon spin rotation (~tSR) techniques in the characterization and classification of superconducting materials. In particular we focus upon the Uemura classification scheme which considers the correlation between the superconducting transition temperature, Tc, and the effective Fermi temperature, TF, determined from IxSR measurements of the penetration depth. Within this scheme strongly correlated "exotic" superconductors, i.e., high T c cuprates, heavy fermions, Chevrel phases and the organic superconductors, forma common but distinct group, characterized by a universal scaling of T c with T r such that 1/100 < Tc/T F < 1/10. For conventiunal BCS superconductors Tc/T F < 1/1000. The results of new ~tSR measurements of the penetration depth in superconducting Y(Nil_xCox)2B2C and YB 6 are also presented. In Y(Nil~COx)2B2C the decrease of T c with increasing Co concentration is linked to a marked decrease in the carrier density from 2.9.1028 m -3 at x = 0 to 0.6.102s m -3 at x = 0.1, while the carrier mass enhancement remains almost constant at approximately 10. For YB 6 we find evidence of a modest enhancement of the carrier mass (m*/m = 3), and a relatively low carrier density of 0.24.102s m -3. These results are discussed within the Uemura classification scheme. It is found that neither Y(Ni I xCox)2B2C with Tc/T F >> 1/250 nor YB 6 with Tc/T F >> 1/340 can be definitively classified as either "exotic" or "conventional", but instead the compounds display behavior which interpolates between the two regimes.