A numerical analysis of natural convective heat transfer in a square porous cavity with a solid wavy finite wall filled with (35% MWCNT-65% Fe3O4)/water hybrid nanofluid. The left wavy wall is heated to a constant temperature, the right wall is held at a low temperature, and the top and bottom walls are thermally insulated. Darcy-Brinkman-Forchheimer model is used to model porous medium with hybrid nanofluid. COMSOL Multiphasic Modeling Software via Galerkin finite element method has been used to solve the governing equations. The dimensionless parameters used in this investigation are; modified Rayleigh number (Ra* = 102, 103, 104, and 106), Darcy number (Da = 10–2, 10–4 and 10–6), Solid volume fraction (ϕ = 0.01, 0.03, and 0.05),undulation number (N = 1, 3, 5, and 7), amplitude of the wavy wall (A = 0.1, 0.2, and 0.3), and Prandtl number = 7.2 at constant high porosity. At a high Darcy number (Da = 10–2), the isotherm lines parallel to the vertical cavity walls, which means that conduction is the primary method of heat transport. At the same time, the convection mode is increasingly necessary at a lower Darcy number. The convection flow and the maximum amounts of stream function are reduced when both A = 0.1 and N = 1 increase. The average Nusselt number increases with increasing Ra*, while it decreases with increasing Darcy number and amplitude wave numbers. It has been determined that the largest improvement in heat transfer is at Ra* = 104, Da = 10–6, ϕ = 0.05, A = 0.1, and N = 1.