In this research, the influence of confined space size on the temperature distribution characteristics of internal window plumes from well-ventilated compartment fires was studied. Theoretical analysis was firstly used to establish a mathematical model for the smoke after ejecting from the window in the space. The study considered fire heat release rate and vertical height as dependent variables. Numerical simulations and experimental methods were carried out to study the temperature variations. A critical distance L2 was obtained. Results show that when the space D between the vertical retaining wall and the building façade is greater than L2, the variation of D has little influence on radial temperature. Once D is less than L2, the radial temperature distribution inside the confined space will tend to be consistent, and the temperature in the confined space sharply increases as D decreases. In addition, a dimensionless model was derived to quantify the relationship between temperature rise and vertical height. The experimental and numerical simulation results were processed, which are in good agreement with the model. The study can provide a framework for managing building safety.