PV/T-TEC collector is a device that can produce thermal energy and electrical energy at the same time. The electrical performance may be increased by absorbing residual heat from the PV surface. Due to the temperature difference available between the hot and cold sides of this collector, additional electrical energy can be also generated by using the TEC to increase the total efficiency. The purpose of this study is to evaluate the thermal effect of using both fins and TECs acting as a heatsink. Thus, the perforated zone with a dimension of 100 x 50 x 2 mm was manufactured by lancing and bending processes. Furthermore, 44 pieces of TECs were placed inside the perforated-finned zone and were attached underneath the PV surface to allow a convection heat transfer process. The model collector was then tested by using a solar simulator under 1100 W/m2 with different fluid mass flow rates ranging from 0 to 0.339 kg/s. To meet the test requirements, environmental fluid flow was also implemented and simulated by a fan with an air velocity of 1 m/s. The results showed that increasing the air mass flow rate as a working fluid by five times can reach the operating temperature of the model collector by about 64 °C (24% decrease) and 74 °C (26% decrease) for both with and without environmental fluid flow, respectively. Meanwhile, under the same test conditions, the maximum value for the temperature difference of TEC sides is found to be 5.6 °C for both with and without ambient fluid flow.