Sizable amount of heavy-quarkonium events can be produced through W -boson decays at the LHC. Such channels will provide a suitable platform to study the heavy-quarkonium properties. The "improved trace technology", which disposes the amplitude M at the amplitude-level, is helpful for deriving compact analytical results for complex processes. As an important new application, in addition to the production of the lower-level Fock states |(QQ ′ )[1S] and |(QQ ′ )[1P ] , we make a further study on the production of higher-excited. Here |(QQ ′ ) stands for the |(cc) -charmonium, |(cb) -quarkonium and |(bb) -bottomonium respectively. We show that sizable amount of events for those higher-excited states can also be produced at the LHC. Therefore, we need to take them into consideration for a sound estimation. If assuming all excited heavy-quarkonium states decay to the ground spin-singlet