Heterobimetallic thiocyanato-bridged coordination polymers based on [Hg(SCN)4]2−: Synthesis, crystal structure, magnetic properties and ESR studies

Heterobimetallic MOFs Containing Tetrathiocyanometallate Building Blocks: Pressure-Induced Spin Crossover in the Porous {FeII(pz)[PdII(SCN)4]} 3D Coordination Polymer

“…For example, a series of CP’s of formula [Ag I x Cu I y (SCN) x+y (pyridine)] and [Cat] 2 [{Cu(NCS)} 3 WS 4 ] have been reported. Similarly, some metal–organic CPs constituted of M I –crown ether complexes (M I = Na, K) and [M II (SCN) 4 ] 2– (M II = Pd, Pt) or [Ir(NCS) 6 ] 3– , Mn II –pyrazol, or Ni II –, Mn II –, and Cu II –imidazole building blocks linked by [Hg(SCN) 4 ] 2– have been reported …”

Dinuclear [CoII(NCMe)5CoII(NCS)4] Possessing Octahedral and Tetrahedral CoII Sites

“…Compounds that possess tetrahedral and octahedral centers are rare and are limited to tetrahedral Hg II S-bound to a thiocyanate bridged to M II (M = Co, Ni,) forming two-dimensional layers with the μ 1,3 -NCS motif. To the best of our knowledge, 1 is the only dinuclear complex with tetrahedral and octahedral geometries in its structure.…”

Structural and magnetic characterizations of the first manganese(iii) Schiff base complexes involving hexathiocyanidoplatinate(iv) bridges

“…On the other hand, only a few complexes have been reported in the literature to date, in which the polythiocyanidometallates behave as bridges, e.g. in Hg(II)-m-SCN-M(II) (M = Ni, Co or Cu), [11][12][13] Mn(II)-m-SCN-Cu(II), 14 Re(II)-m-SCN-M(II) (M = Co, Fe, Ni or Mn) 15 and Mo(III)-m-SCN-M(II) (M = Co or Ni). 16 Till now, there is only one Mn(II) compound bridged by the tetrathiocyanidoplatinate(II) anion reported in the literature.…”