Heterointerface engineering of Rh/Pd metallene for hydrazine oxidation-assisted energy-saving hydrogen production

Abstract

Heterointerface Rh/Pd metallene is synthesized for hydrazine oxidation-assisted water splitting, requiring a low potential of 0.19 V at 100 mA cm−2 for energy-saving hydrogen production.

NiFeP nanosheets for efficient and durable hydrazine-assisted electrolytic hydrogen production

“…19–22 Moreover, the anode electrolysis product is N 2 , which can avoid the potentially dangerous problem caused by mixing of oxygen and hydrogen. 23…”

Highly bifunctional Rh2P on N,P-codoped carbon for hydrazine oxidation assisted energy-saving hydrogen production

“…S2 (ESI†) reveals that non-uniform Rh nanoparticles of several nanometers were observed for Rh/C, and the apparent lattice spacing of 0.220 nm is attributed to the (111) lattice plane of Rh. 30 As for NPC, the flakes with rough surfaces were found to have disordered lattice fringes of graphene and uniform N and P doping (Fig. S3, ESI†).…”

Trapping molecular hydrazine in a cocrystal via hydrogen bonding

“…Since the first discovery of hydrazine (N 2 H 4 ) by Curtius in 1887, it has been extensively utilized as an industrial chemical for diverse organic products, 1 serving as a raw source for hydrogen production, 2 and notably emerging as an efficient fuel in liquid rocket propellants since World War II. 3 However, with the rise of sustainable development and green chemistry, the applications of hydrazine face impediments due to its inherent hazardous properties, including instability, volatility, flammability in the absence of air, and high toxicity.…”