Heteroleptic platinum(II) complexes with crown thioethers and diimine ligands: the crystal structures of [Pt(9S3)(2,2′-bipy)](PF6)2 and [Pt(9S3)(4,4-dimethyl-2,2′-bipy)](PF6)2·2.5CH3NO2

A Cyclometallated (Azobenzene)palladium(II) Complex of 1,4,7‐Trithiacyclononane: Synthesis and Reactivity with Thioether‐Dithiolate Metalloligands, Single‐Crystal X‐ray Diffraction Analyses and Electrochemical Studies

“…There are clear variations in the bond parameters of the geometrically identical cations of 6A and the different solvates of 6B . Thus, the Pd–S(1) distances range from 2.276(2) to 2.3052(6) Å, similar to those in 1 and 2 7b and in non‐cyclometallated complexes;5e,6a,6b the Pd–S(2) distances range from 2.3781(7) to 2.418(2) Å (those of 1 and 2 are within this range and slightly lower, respectively). The Pd(1)–S(3) bonds are significantly longer (by 0.32–0.56 Å), more variable (variation of 0.1345 Å), and are slightly shorter than those in Grant's compounds.…”

Pnictogen–thiacrown complexes with Pt(ii) and Pd(ii)

“…A subsequent report of Pt(II) [9]aneS 3 involving substituted 2,2′-bipyridine complexes by the Grant group appeared. 23 Concurrently, the Connick group prepared similar complexes, generated by their interest in photochemical applications. 24 The substituted bipyridines from both papers are shown in Scheme 2.…”

“…18 Pd(II) complexes in that both an oxidation and a reduction wave are observed, but neither are reversible. 23,24 Connick and coworkers noted that the room temperature absorption spectra for the bipy and dimethyl-substituted complexes in MeCN display a broad and relatively low energy metal-ligand charge transfer (MLCT) transition near 390 nm. However, the electron-withdrawing properties of the -CF 3 group in its substituted bipy complexes resulted in an unusual red shift of the MLCT band to 460 nm and a lowered extinction coefficient by about one-half.…”

New Pd(II) and Pt(II) complexes with N,S-chelated pyrazolonate ligands: Molecular and supramolecular structure and preliminary study of their in vitro antitumoral activity

“…The spectra of ½PtL 2 2 and ½PtL 5 2 each show just one signal and this has a chemical shift similar to those found in other complexes with [PtN 2 S 2 ] kernels (ca. -3150 ppm) [33][34][35].…”