Hexaaquanickel(II) bis(dimethyl phosphate)

Abstract

Key indicatorsSingle-crystal X-ray study T = 115 K Mean (O-C) = 0.003 Å R factor = 0.036 wR factor = 0.085 Data-to-parameter ratio = 19.4For details of how these key indicators were automatically derived from the article, see

Synthesis, Characterization, and Crystal Structures of a New Coordination Polymer of Manganese(II) Containing Dimethyl Phosphate

“…On the other hand, several rhombics formed a staircase pipe, where connected by four DMP bridges in zic-zac form. The Mn-O and P-O bond lengths ( [38]. The phosphate groups, in this complex, are arranged as an abnormal distorted tetrahedron.…”

“…Moreover, in addition to phosphate and phosphate ester complexes; complexes incorporating nucleic acid fragments, ATP, polyphosphates, and polyphosphate esters have been structurally characterized [29Ϫ33]. Recently, we have reported the synthesis and crystal structure of [La(µ-DMP) 2 (µ 3 -NO 3 )(DMSO)] n [34] [UO 2 (µ-DEP) 4 2 as an ionic complex [40]. In this complex, DMP is not bonded to the metal atom, and acts as a independent counter-ion.…”

Poly[[aquatris(μ-dimethyl phosphato-κ2O,O′)bis(μ-dimethyl sulfoxide-κO)(dimethyl sulfoxide-κO)dimanganese(II)] nitrate monohydrate]

“…In a recent paper, we reported the synthesis and crystal structure of [Ni(H 2 O) 6 ](DMP) 2 (Rafizadeh & Amani, 2006a), where DMP is the dimethyl phosphate anion, [O 2 P(OCH 3 ) 2 ] À . In this compound, DMP is not bonded to the metal and acts as a counter-ion.…”

Synthesis, Characterization, and Crystal Structures of Novel Coordination Polymers of Praseodymium(III) and Neodymium(III) Containing Dialkyl Phosphate

“…Mononuclear, 37 In this complex, DMP is not bonded to the metal, and acts as a independent counter-ion. We have also reported the synthesis and crystal structures of [Fe 16 …”

“…Also, we reported the synthesis and crystal structures of [Ni(H 2 O) 6 ](DMP) 2 as an ionic complex. 37 In this complex, DMP is not bonded to the metal, and acts as a independent counter-ion. We have also reported the synthesis and crystal structures of [Fe 16 (µ 3 -O) 8 (µ 3 -OH) 4 (µ-OH) 4 (µ-DMP) 12 (µ-OAc) 12 -(DMSO)4]․2DMSO ․1.5H2O, 38 within which an macromolecule constellation consisting of sixteen iron ion connected by twelve bridging dimethyl phosphate, twelve bridging acetate, eight µ3-oxo, four µ3-OH, four µ-OH and four dimethyl sulfoxide ligands.…”