Hierarchically porous adsorbent alginate beads incorporating poly(3, 4-ethylenedioxythiophene) for dispersive liquid-solid phase extraction of five polycyclic aromatic hydrocarbons

Jullakan, Sirintorn; Pinsrithong, Sakchaibordee; Bunkoed, Opas

doi:10.1016/j.jfca.2022.104629

Journal of Food Composition and Analysis

2022

DOI: 10.1016/j.jfca.2022.104629

|View full text |Cite

Hierarchically porous adsorbent alginate beads incorporating poly(3, 4-ethylenedioxythiophene) for dispersive liquid-solid phase extraction of five polycyclic aromatic hydrocarbons

Sirintorn Jullakan

Sakchaibordee Pinsrithong

Opas Bunkoed

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2022

2024

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 10 publications

References 52 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Microgels based on thermo‐responsive poly(N‐isopropylacrylamide) as sorbent of bisphenol A and parabens in water

Leite,

Sampaio,

de Oliveira

et al. 2024

Journal of Polymer Science

View full text Add to dashboard Cite

Smart microgels can be used as sorbents, possessing high surface area and rapid stimuli‐responsiveness. A series of poly(N‐isopropylacrylamide) (pNIPAM) and pNIPAM‐co‐starch nanoparticles (pNIPAM‐co‐SNPs) thermo‐responsive microgels were synthesized, presenting different hydrophilic/hydrophobic behavior according to the composition. The adsorption studies were carried out for methylparaben (MPB), ethylparaben (EPB), propylparaben (PPB), butylparaben (BPB), and bisphenol A (BPA), and the extraction and desorption efficiency were determined by high‐performance liquid chromatography and spectrophotometric detection (HPLC‐UV). The effect of microgel phase transition according to the temperature and the copolymerization with SNPs in each sorptive step was investigated. The extraction of less polar compounds (BPA, PPB, and BPB) above the volume phase transition temperature (VPTT) was favored, driven by a predominant hydrophobic interaction. According to microgel composition, the desorption capacity as a function of temperature can be influenced by hydrophilic interactions and water competition. Molecular dynamics (MD) simulations and binding free energy calculations were performed to provide theoretical evidence about binding energies between pNIPAM and BPA, which experimentally showed the best extraction efficiency results. These findings may provide a strategy for designing high‐performance sorptive phases that could remove hydrophilic and hydrophobic compounds from water and a hypothesis about the driving forces of such processes.

show abstract

Microgels based on thermo‐responsive poly(N‐isopropylacrylamide) as sorbent of bisphenol A and parabens in water

Leite,

Sampaio,

de Oliveira

et al. 2024

Journal of Polymer Science

View full text Add to dashboard Cite

show abstract

In situ anchor of multi-walled carbon nanotubes into iron-based metal-organic frameworks for enhanced adsorption of polycyclic aromatic hydrocarbons by magnetic solid-phase extraction

Yang

Zhang

Wang

et al. 2022

Journal of Chromatography A

View full text Add to dashboard Cite

Preparation and application of bimetallic coordination cluster Cu7Mn2 for dispersive solid phase extraction of polycyclic aromatic hydrocarbons in lettuce

Zhang

Chen

et al. 2023

Journal of Food Composition and Analysis

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Hierarchically porous adsorbent alginate beads incorporating poly(3, 4-ethylenedioxythiophene) for dispersive liquid-solid phase extraction of five polycyclic aromatic hydrocarbons

Cited by 10 publications

References 52 publications

Microgels based on thermo‐responsive poly(N‐isopropylacrylamide) as sorbent of bisphenol A and parabens in water

Microgels based on thermo‐responsive poly(N‐isopropylacrylamide) as sorbent of bisphenol A and parabens in water

In situ anchor of multi-walled carbon nanotubes into iron-based metal-organic frameworks for enhanced adsorption of polycyclic aromatic hydrocarbons by magnetic solid-phase extraction

Preparation and application of bimetallic coordination cluster Cu7Mn2 for dispersive solid phase extraction of polycyclic aromatic hydrocarbons in lettuce

Contact Info

Product

Resources

About