2021
DOI: 10.1016/j.isci.2021.102547
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High-capacity and high-rate Ni-Fe batteries based on mesostructured quaternary carbon/Fe/FeO/Fe3O4 hybrid material

Abstract: Summary The Ni-Fe battery is a promising alternative to lithium ion batteries due to its long life, high reliability, and eco-friendly characteristics. However, passivation and self-discharge of the iron anode are the two main issues. Here, we demonstrate that controlling the valence state of the iron and coupling with carbon can solve these problems. We develop a mesostructured carbon/Fe/FeO/Fe 3 O 4 hybrid by a one-step solid-state reaction. Experiment… Show more

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Cited by 22 publications
(11 citation statements)
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“…The content of Fe in IONCNs was measured to be 23.07%. Fe 2p 3/2 and Fe 2p 1/2 (Figure c) further revealed that Fe in the IONCNs was composed of Fe 2+ and Fe 3+ , indicating the existence of redox couples. , …”
Section: Resultsmentioning
confidence: 79%
See 1 more Smart Citation
“…The content of Fe in IONCNs was measured to be 23.07%. Fe 2p 3/2 and Fe 2p 1/2 (Figure c) further revealed that Fe in the IONCNs was composed of Fe 2+ and Fe 3+ , indicating the existence of redox couples. , …”
Section: Resultsmentioning
confidence: 79%
“…Fe 2p 3/2 and Fe 2p 1/2 (Figure 3c) further revealed that Fe in the IONCNs was composed of Fe 2+ and Fe 3+ , indicating the existence of redox couples. 49,50 The saturation magnetization of the IONCNs was measured to be 25.59 emu g −1 (Figure 3d). In addition, the IONCNs had no obvious coercivity or remanence, revealing its superparamagnetic behavior at room temperature (inset of Figure 3d).…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…O acoplamento físico fraco entre o carbono e os materiais ativos pode limitar as reações para uma transferência de carga eficiente. Além do mais, devido à alta hidrofobicidade dos nanocarbonos, é difícil obter uma distribuição uniforme de carbono em compósitos por mistura física [15].…”
Section: Novos Materiais Ativos Aplicados Em Baterias Níquel-ferrounclassified
“…Lastly, nickel is substantially more expensive than lead. Their key benefits are greater power density in comparison to lead-acid batteries and the capacity to resist 2000 severe discharges [24].…”
Section: Nickel/ironmentioning
confidence: 99%