High capacity Li[Li0.2Mn0.54Ni0.13Co0.13]O2–V2O5 composite cathodes with low irreversible capacity loss for lithium ion batteries

Gao, Jie; Kim, J.; Manthiram, Arumugam

doi:10.1016/j.elecom.2008.10.036

Cited by 153 publications

(66 citation statements)

References 16 publications

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“…From the electrochemical point of view, it has been demonstrated that the performance of LNMCO in highpower lithium-ion batteries is strongly dependent on the structural properties [30][31][32][33][34]. The main problem that still needs to be solved for such applications of LNMCO is the cation mixing between nickel and lithium-ions since the ionic radius of Ni 2+ (0.69Å) is close to that of Li + (0.76Å) for CN=6 [35].…”

Section: Introductionmentioning

confidence: 97%

Structural and electrochemical properties of LiNi1/3Co1/3Mn1/3O2 material prepared by a two-step synthesis via oxalate precursor

Hashem

El-Taweel

Abuzeid

et al. 2011

Ionics

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LiNi 1/3 Co 1/3 Mn 1/3 O 2 (LNMCO) powders were formed by a two-step synthesis including preparation of an oxalate precursor by "chimie douce" followed by a solidstate reaction with lithium hydroxide. The product was characterized by TG-DTA, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR), Raman spectroscopy, electron spin resonance (ESR), and SQUID magnetometry. XRD data revealed well-crystallized layered LNMCO with α-NaFeO 2 -type structure (R-3 m space group). Morphology studied by SEM and TEM shows submicronic particles of 400-800 nm with a tendency to agglomerate. The local structure investigated by vibrational spectroscopy (FTIR, Raman), ESR, and SQUID measurements confirms the well-crystallized lattice with a cation disorder of 2.6% Ni 2+ ions in Li(3b) sites. Electrochemical tests were carried out in the potential range 2.5-4.5 V vs. lithium metal on samples heated at 900°C for 12 h. Initial discharge capacity is 154 mAh/g at C/5, while a capacity of 82 mAh/g is still delivered at 10

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Section: Introductionmentioning

confidence: 97%

Structural and electrochemical properties of LiNi1/3Co1/3Mn1/3O2 material prepared by a two-step synthesis via oxalate precursor

Hashem

El-Taweel

Abuzeid

et al. 2011

Ionics

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“…However, it is well known that pristine bulk V 2 O 5 is not an appropriate cathode material because of its low lithium diffusion coefficient and poor structural stability with lithium insertion/extraction, which lead to bad battery performance such as poor capacity retention and low rate capability. Recently, many studies have been focused on the composite or novel structured V 2 O 5 cathode materials [5][6][7][8]. Especially, the nanostructured materials exhibit better electrochemical performance with respect to bulk V 2 O 5 by virtue of their morphology properties.…”

Section: Introductionmentioning

confidence: 99%

Structural and electrochemical properties of Al3+ doped V2O5 nanoparticles prepared by an oxalic acid assisted soft-chemical method

Zhan

Wei

Bie

et al. 2010

Journal of Alloys and Compounds

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“…[45] Surface coating provides structural stability, slows oxygen evolution, and maintains the vacancies that are formed, thereby reducing the irreversible capacity. The coatings include metal oxides such as Al 2 O 3 , V 2 O 5 , etc., [46,47] and metal phosphates such as AlPO 4 and CoPO 4 . [48] Manthiram and co-workers showed a low irreversible capacity of about 41 mA h g −1 for Li 1 [49] Li-insertion hosts can help in capturing the Li + ions that cannot be intercalated into the Li-, Mn-rich oxide structure during the discharge process.…”

Section: Challenges For Li- Mn-rich Layered Oxides For Practical Appmentioning

confidence: 99%

Review on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li‐ and Mn‐Rich Cathode Materials for Li‐Ion Batteries

Nayak

Erickson

Schipper

et al. 2017

Advanced Energy Materials

520

304

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CO 2 emissions. Hence, transportation dependent on electrical propulsion (electric vehicles) instead of internal combustion engines can greatly reduce the pollution caused by our transportation infrastructure. While rechargeable Li-ion batteries are the major power source for portable electronic devices such as smartphones and laptop computers, further improvements in their energy density is required in order to promote electrochemical propulsion devices that can compete with internal combustion engines. [1] The energy density of Li-ion batteries depends on the specific capacities and redox potentials of their electrode materials. Layered lithiated transition metal oxides such as LiCoO 2 , LiNi 1/2 Mn 1/2 O 2 , and LiNi 1/3 Mn 1/3 Co 1/3 O 2 ("NMC 111") were extensively studied as cathodes, which can exhibit specific capacities ≤160 mA h g −1 with an upper potential limit of 4.3 V versus Li. [2] The high cost, low thermal stability, and fast capacity fading at high current rates or during deep cycling of currently used LiCoO 2 necessitated the development of other layered cathodes, such as LiNi 1/2 Mn 1/2 O 2 , NMC 111, etc. The electrochemical performance of these layered metal oxides was recently reviewed by Yushin and coworkers. [3] Higher capacities can be extracted from layered metal oxide cathodes by cycling to upper potentials of about 4.5 V, however, driving these layered cathode materials to such high potentials enhances the structural instability and impedance growth. [4,5] Another important direction is the development of Ni-rich NCM cathode materials. As the content of Ni is higher, the specific capacity that can be extracted is higher as

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High capacity Li[Li0.2Mn0.54Ni0.13Co0.13]O2–V2O5 composite cathodes with low irreversible capacity loss for lithium ion batteries

Cited by 153 publications

References 16 publications

Structural and electrochemical properties of LiNi1/3Co1/3Mn1/3O2 material prepared by a two-step synthesis via oxalate precursor

Structural and electrochemical properties of LiNi1/3Co1/3Mn1/3O2 material prepared by a two-step synthesis via oxalate precursor

Structural and electrochemical properties of Al3+ doped V2O5 nanoparticles prepared by an oxalic acid assisted soft-chemical method

Review on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li‐ and Mn‐Rich Cathode Materials for Li‐Ion Batteries

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