High-capacity organic sodium ion batteries using a sustainable C4Q/CMK-3/SWCNT electrode

Yan, Bing; Wang, Lijiang; Huang, Weiwei; Zheng, Shibing; Hu, Pandeng; Du, Yuyu

doi:10.1039/c9qi00507b

Cited by 43 publications

(40 citation statements)

References 31 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Up to now, organic small molecules with different groups, including CO (quinones and ketones, carboxylates, anhydrides, and imides derivatives), CN (Schiff, pteridine derivatives), and NN (azo derivatives) bond compounds, have been proved to be electroactive electrode materials for SIBs. Among them, the carbonyl compounds containing CO bond is the most widely studied organic electrode materials, because of their unique multielectron reaction, high theoretical capacity and a wide structural diversity . Schiff and pteridine derivatives containing CN bond has an adjustable electrochemical activity, in which plane structure and conjugated structure play an important role in stabilizing their electrochemical activity .…”

Section: Research Progress Of Organic Electrode Materialsmentioning

confidence: 99%

“…Particularly the application of new azo compounds and MOFs as OSIB materials are also included in this review. Among them, organic small‐molecular materials include mainly three different classes: carbonyl compounds (CO), Schiff and pteridine derivatives (CN), and azo derivatives (NN) . In carbonyl (CO) compounds, quinones and ketones demonstrate higher redox potential, carboxylic acids however possess lower Na insertion voltage, while the anhydride compounds are recognized by their high specific capacity and long cycle life.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Recent Progress in Advanced Organic Electrode Materials for Sodium‐Ion Batteries: Synthesis, Mechanisms, Challenges and Perspectives

Yin

Sarkar

Shi

et al. 2020

Adv Funct Materials

215

113

View full text Add to dashboard Cite

Rechargeable sodium‐ion batteries (SIBs) are considered attractive alternatives to lithium‐ion batteries for next‐generation sustainable and large‐scale electrochemical energy storage. Organic sodium‐ion batteries (OSIBs) using environmentally benign organic materials as electrodes, which demonstrate high energy/power density and good structural designability, have recently attracted great attention. Nevertheless, the practical applications and popularization of OSIBs are generally restricted by the intrinsic disadvantages related to organic electrodes, such as their low conductivity, poor stability, and high solubility in electrolytes. Here, the latest research progress with regard to electrode materials of OSIBs, ranging from small molecules to organic polymers, is systematically reviewed, with the main focus on the molecular structure design/modification, the electrochemical behavior, and the corresponding charge‐storage mechanism. Particularly, the challenges faced by OSIBs and the effective design strategies are comprehensively summarized from three aspects: function‐oriented molecular design, micromorphology regulation, and construction of organic–inorganic composites. Finally, the perspectives and opportunities in the research of organic electrode materials are discussed.

show abstract

Section: Research Progress Of Organic Electrode Materialsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Recent Progress in Advanced Organic Electrode Materials for Sodium‐Ion Batteries: Synthesis, Mechanisms, Challenges and Perspectives

Yin

Sarkar

Shi

et al. 2020

Adv Funct Materials

215

113

View full text Add to dashboard Cite

show abstract

“…These results demonstrate that immobilizing active materials by carbon materials also has excellent effects on enhancing the electrochemical properties of SIBs. In addition, the ternary composite C4Q/CMK‐3/SWCNTs also can be applied to SIBs . For the first cycle at 0.1 C, the capacity was 441 mAh g −1 and remained 75 % after 50 cycles.…”

Section: Applications In Sibsmentioning

confidence: 99%

“…Reproduced by permission of The Royal Society of Chemistry. b) Cycle performance of C4Q/CMK‐3/SWCNTs composite . Reproduced by permission of The Royal Society of Chemistry.…”

Section: Applications In Sibsmentioning

confidence: 99%

Recent Progress in Calix[n]quinone (n=4, 6) and Pillar[5]quinone Electrodes for Secondary Rechargeable Batteries

Zhang

Huang

et al. 2020

Batteries & Supercaps

Self Cite

View full text Add to dashboard Cite

Attributing to the advantages of high theoretical specific capacity, good structural designability and environmental friendliness, organic quinone electrode materials have been applied in secondary batteries to achieve great electrochemical performances. At present, a series of researches about secondary batteries with quinone‐based compounds calix[4]quinone (C4Q), pillar[5]quinone (P5Q) and calix[6]quinone (C6Q) as cathodes have been carried out. In this review, we systematically summarize the applications of these three types of quinone compounds in lithium‐ion batteries (LIBs), sodium‐ion batteries (SIBs), zinc‐ion batteries (ZIBs), and magnesium‐ion batteries (Mg‐ion batteries). The optimizing methods for suppressing the dissolution of organic electrode materials such as quasi‐solid‐state electrolytes, all‐solid‐state electrolytes, ionic liquid electrolytes, aqueous electrolytes and carbon immobilization are concluded. This review could provide a good guideline to improve the electrochemical performances of secondary batteries using quinone compounds as cathodes in the future.

show abstract

“…Nevertheless, the high volatility and solubility [28] of quinone greatly limit its usage in LIBs. Up to now, anthraquinone (AQ) [28], dibenzothiophene (DBT) [28], calix[4]quinone (C4Q) [29][30][31][32], pillar[5]quinone (P5Q) [33,34] and several other quinones derivatives have been widely reported. Huang et al [29] first applied C4Q as cathode in LIBs and found that C4Q could deliver an initial capacity of 431 mA h g −1 (97% of C theo ) in the liquid electrolytes; however, the batteries only preserved a capacity approximating to 100 mA h g −1 after five cycles.…”

Section: Introductionmentioning

confidence: 99%

Calix[6]quinone as high-performance cathode for lithium-ion battery

et al. 2019

Self Cite

View full text Add to dashboard Cite

Organic quinone compounds have attracted wide attention due to their high theoretical capacities. Here, a novel cyclic macromolecular calix[6]quinone (C6Q), which possesses 6 p-quinone units and can provide 12 electrochemical active sites, has been applied as a promising cathode material in lithium ion batteries (LIBs). The as-fabricated LIBs exhibited an initial specific capacity as high as 423 mA h g −1 (C theo = 447 mA h g −1) at 0.1 C. After 100 cycles, the capacity of C6Q maintained at 216 mA h g −1 , and even after 300 cycles, C6Q still achieved a high specific capacity of 195 mA h g −1 with negligible capacity fading (as compared with the 100 th cycle). Due to the large capacity and wide electrochemical window, C6Q can deliver a specific energy up to 1201 W h kg −1. In addition, the method of immobilizing C6Q with ordered mesoporous carbon (OMC) CMK-3 could further enhance the electrochemical performance of C6Q.

show abstract

High-capacity organic sodium ion batteries using a sustainable C4Q/CMK-3/SWCNT electrode

Abstract: SWCNTs formed a three-dimensional conductive network between C4Q/CMK-3 nanocomposites, significantly improving the electrochemical performance of C4Q-SIBs.

Cited by 43 publications

References 31 publications

Recent Progress in Advanced Organic Electrode Materials for Sodium‐Ion Batteries: Synthesis, Mechanisms, Challenges and Perspectives

Recent Progress in Advanced Organic Electrode Materials for Sodium‐Ion Batteries: Synthesis, Mechanisms, Challenges and Perspectives

Recent Progress in Calix[n]quinone (n=4, 6) and Pillar[5]quinone Electrodes for Secondary Rechargeable Batteries

Calix[6]quinone as high-performance cathode for lithium-ion battery

Contact Info

Product

Resources

About